S-(三氟甲基)二苯并噻吩三氟甲基磺酸盐

S-(三氟甲基)二苯并噻吩三氟甲基磺酸盐结构式
S-(三氟甲基)二苯并噻吩三氟甲基磺酸盐结构式
品牌特惠专场 		常用名 S-(三氟甲基)二苯并噻吩三氟甲基磺酸盐 英文名 S-(Trifluoromethyl)dibenzothiophenium trifluoromethanesulfonate
CAS号 129946-88-9 分子量 402.332
密度 7 g/cm3 沸点 N/A
分子式 C14H8F6O3S2 熔点 155 °C
MSDS 中文版 美版 闪点 N/A
符号 GHS07
GHS07		 信号词 Warning
Pd(II)-catalyzed ortho trifluoromethylation of arenes and insights into the coordination mode of acidic amide directing groups.

J. Am. Chem. Soc. 29th ed., 134 , 11948-11951, (2012)

A Pd(II)-catalyzed trifluoromethylation of ortho C-H bonds with an array of N-arylbenzamides derived from benzoic acids is reported. N-Methylformamide has been identified as a crucial promoter of C-CF(3) bond formation from the Pd center. X-ray characterizati...

Copper-catalyzed trifluoromethylation of terminal alkynes using Umemoto's reagent Luo, D.-F.; et al.

Tetrahedron Lett. 22th ed., 53 , 2769-2772, (2012)

Ionic liquids as new media for electrophilic trifluoromethylation reactions Pegot, B.; et al.

J. Fluor. Chem. 134 , 156-159, (2012)

Copper-catalyzed trifluoromethylation of terminal alkenes through allylic C-H bond activation.

J. Am. Chem. Soc. 39th ed., 133 , 15300-15303, (2011)

An unprecedented type of reaction for Cu-catalyzed trifluoromethylation of terminal alkenes is reported. This reaction represents a rare instance of catalytic trifluoromethylation through C(sp(3))-H activation. It also provides a mechanistically unique exampl...