Study of chiroptical properties of some piperidine derivatives

O Červinka, A Fábryová, V Šňupárek…

文献索引：Cervinka, Otakar; Fabryova, Anna; Snuparek, Vladimir; Strejcek, Fratisek Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # 6 p. 1624 - 1634

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被引用次数: 1

摘要

Abstract Chiroptical properties of (S)-(-)-1-methyl-2-phenylpiperidine and (S)-(-)-1-methyl-2- (2-tolyl) piperidine have been studied. The preferred conformations have been calculated in gradient way on the basis of the CNDO/2 method, and the rotational forces have been calculated for them by direct procedure using the CNDO/S-CI wave function. For comparison of theory and experiment, molar fractions of the individual conformers have been ...