Electroorganic chemistry. XXI. Selective formation of. alpha.-acetoxy ketones and general synthesis of 2, 3-disubstituted 2-cyclopentenones through the anodic …

T Shono, M Okawa, I Nishiguchi

文献索引：Shono,T. et al. Journal of the American Chemical Society, 1975 , vol. 97, p. 6144 - 6147

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被引用次数: 60

摘要

Abstract: The anodic oxidation of enol acetates in acetic acid gave two types of products, namely a-acetoxy ketones (type A) and a,@-unsaturated enones (type B), and their distribution was remarkably influenced by the character of the supporting electrolyte. In the anodic oxidation of a-alkylated alicyclic enol acetates, the exclusive formation of a,@- unsaturated enones in an excellent yield was achieved by the use of tetraethylammonium ...