The synthesis of cyclic alcohols and olefins by the interaction of dimagnesium halides and esters

CD Nenitzescu, I Necsoiu

文献索引：Nenitzescu; Necsoiu Journal of the American Chemical Society, 1950 , vol. 72, p. 3483

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被引用次数: 25

摘要

Summary The dextrorotatory sirup obtained as a byproduct with tetraacetyl-pD- glucopyranosylben-zene by the action of phenylmagnesium bromide on tetraacetyl-aD- glucopyranosyl bromide has been deacetylated to yield aD-glucopyranosylbenzene. The acetate and methyl ether derivatives of this compound are described, along with tetramethyl- pD-glucopyranosylbenzene. The application of Hudson's rules of isorotation to the ...