Acyclic stereoselection. 25. Stereoselective synthesis of the C-1 to C-7 moiety of erythronolide A

CH Heathcock, SD Young, JP Hagen…

文献索引：Heathcock, Clayton H.; Young, Steven D.; Hagen, James P.; Pilli, Ronaldo; Badertscher, Ulrich Journal of Organic Chemistry, 1985 , vol. 50, # 12 p. 2095 - 2105

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被引用次数: 68

摘要

A stereoselective synthesis of aldehyde ester 1, a synthon for the C-1 to C-7 section of erythronolide A, is reported. The synthesis begins with P, y-unsaturated aldehyde 12, which is prepared from mesityl oxide as shown in eq 2. Aldehyde 12 reacts with the preformed ...