Aluminium-chloride-promoted reactions of ethyl acrylate with olefins

ALJ Beckwith, G Moad

文献索引：Beckwith,A.L.J.; Moad,G. Australian Journal of Chemistry, 1977 , vol. 30, p. 2733 - 2739

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被引用次数: 12

摘要

Abstract Contrary to an earlier report, 1 the aluminium-chloride-promoted reaction of ethyl acrylate with olefins does not afford cyclobutane derivatives. In benzene, ethyl acrylate reacts with isobutylene or 2, 3-dimethylbut-2-ene to afford the terminally unsaturated products (5) and (9) respectively. In 1, 2-dichloroethane-nitromethane the initial products undergo isomerization or rearrangement. Un-ambiguous routes to 2, 2- ...