... c1 effects a decrease of the interplanar angle /3. Therefore, the exocyclic bonds at the bridgehead carbon atoms of the pyrimidine rings are bent less (range of p: 9.0- 5.9") than in [2.2] paracyclophane (p = ll.2 ... Related phanes, [2.2](2,5)- "81 c171 9 1 14.ba ... 123 (1990) 1885-1889 ...