“Donor–Acceptor” Oligogermanes: Synthesis, Structure, and Electronic Properties

KV Zaitsev, AA Kapranov, AV Churakov…

文献索引：Schaefer, Annemarie; Weidenbruch, Manfred; Peters, Karl; Schnering, Hans Georg von Angewandte Chemie, 1984 , vol. 96, # 4 p. 311 - 312

全文：HTML全文

被引用次数: 12

摘要

... At the same time, a significant change in the structural parameters for (C 6 F 5 ) 4 Ge(31) and (C 6 F 5 ) 3 GeCl (3) (d(Ge–C) = 1.956(4) vs 1.9391(15) Å; ∠(C–Ge–C) av = 105.0(2) vs 112.85(4)°, respectively) is due to a decrease of the steric volume of chlorine. ...