Chemistry Letters

REDUCTIVE CONVERSION OF NITRO ALKENES TO KETONES AND/OR OXIMES IN AN AQUEOUS HClO 4–CH 2 Cl 2–DIOXANE–(Pb) SYSTEM

S Torii, H Tanaka, T Katoh

文献索引：Torii, Sigeru; Tanaka, Hideo; Katoh, Tetsuo Chemistry Letters, 1983 , p. 607 - 610

全文：HTML全文

被引用次数: 18

摘要

Electrochemical and chemical reduction of nitro alkenes in an aqueous HClO 4–CH 2 Cl 2– dioxane–(Pb) system afforded ketones and oximes in good yields, each of which can be obtained selectively by treating with either aqueous formaldehyde or hydroxylamine as a proper workup process, respectively.

 相关合成线路
1-methoxy-4-(2-nitro-1(Z)-propenyl)benzene结构式

207511-16-8

1-methoxy-4-(2-...

~88%

1-(4-Methoxyphenyl)acetoneoxime结构式

52271-41-7

1-(4-Methoxyphe...

(Z)-2-nitronon-2-ene结构式

121190-61-2

(Z)-2-nitronon-2-ene

~90%

2-壬酮结构式

821-55-6

2-壬酮

(Z)-2-Nitro-1-phenyl-1-propene结构式

58321-79-2

(Z)-2-Nitro-1-p...

~73%

2-Propanone, 1-phenyl-,oxime结构式

13213-36-0

2-Propanone, 1-...

1-methoxy-4-(2-nitro-1(Z)-propenyl)benzene结构式

207511-16-8

1-methoxy-4-(2-...

~85%

对甲氧基苯基丙酮结构式

122-84-9

对甲氧基苯基丙酮

1-chloro-4-(2-nitro-1(Z)-propenyl)benzene结构式

1163136-86-4

1-chloro-4-(2-n...

~89%

(4-chlorophenyl)acetone oxime结构式

1454-65-5

(4-chlorophenyl...