Highly selective allylic alkylation with a carbon nucleophile at the more substituted allylic terminus catalyzed by an iridium complex: an efficient method for constructing …

R Takeuchi, M Kashio

文献索引：Takeuchi; Kashio Angewandte Chemie - International Edition in English, 1997 , vol. 36, # 3 p. 263 - 265

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被引用次数: 169

摘要

Iridium complexes have been studied as models for intermediates in catalytic reactions. For example, the oxidative addition reaction of [IrCI (CO)(PPh,), J is well known."] Since Crabtree reported that a cationic iridium complex is a highly active catalyst for hydrogenation of alkenes,''] iridium complexes have received much attention as potential hydrogenation catalysts. Recently an iridium complex catalyzed asymmetric hydrogenation was reported. ...