Oxidations by the reagent “O 2–H 2 O 2–vanadium derivative–pyrazine-2-carboxylic acid”. Part 12. 1 Main features, kinetics and mechanism of alkane …

…, S Stanislas, A Kitaygorodskiy, VS Kulikova

文献索引：Shul'pin, Georgiy B.; Kozlov, Yuriy N.; Nizova, Galina V.; Suess-Fink, Georg; Stanislas, Sandrine; Kitaygorodskiy, Alex; Kulikova, Vera S. Journal of the Chemical Society. Perkin Transactions 2, 2001 , # 8 p. 1351 - 1371

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被引用次数: 143

摘要

Various combinations of vanadium derivatives (n-Bu4NVO3 is the best catalyst) with pyrazine-2-carboxylic acid (PCA) catalyse the oxidation of saturated hydrocarbons, RH, with hydrogen peroxide and air in acetonitrile solution to produce, at temperatures< 40° C, alkyl hydroperoxides, ROOH, as the main primary products. These compounds are easily reduced with triphenylphosphine to the corresponding alcohols, which can then be ...