Aerobic Oxidation of Amines Catalyzed by Polymer-Incarcerated Au Nanoclusters: Effect of Cluster Size and Cooperative Functional Groups in the Polymer

…, M Morita, T Inasaki, S Kobayashi

文献索引：Miyamura, Hiroyuki; Morita, Masataka; Inasaki, Takeshi; Kobayashi, Shu Bulletin of the Chemical Society of Japan, 2011 , vol. 84, # 6 p. 588 - 599

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被引用次数: 41

摘要

Aerobic oxidation reaction of amines to imines catalyzed by polymer-incarcerated Au nanoclusters (PI-Au) was developed. The effect of cluster size for this oxidation reaction was carefully examined using the same polymer support. We have succeeded in preparation of various PI-Au catalysts containing different size clusters by modification of standard preparation methods. The size of clusters and their distribution were analyzed by electron ...