Chemistry Letters

A Facile Method for Synthesis of Alkyl Phenyl Selenides. The Reaction of Diphenyl Diselenide with Oxygen-containing Compounds Using La/Me3SiCl/cat. I2/cat. CuI …

T Nishino, Y Nishiyama, N Sonoda

文献索引：Nishino, Toshiki; Nishiyama, Yutaka; Sonoda, Noboru Chemistry Letters, 2003 , vol. 32, # 10 p. 918 - 919

被引用次数: 12

摘要

Alcohols, ethers, and esters were directly converted to the corresponding alkyl phenyl selenides by the reaction of diphenyl diselenide and the La/Me 3 SiCl/cat. I 2/cat. CuI. It was suggested that alkyl phenyl selenides were formed by the SH 2 type reaction of diphenyl diselenide with alkyl radicals generated from alcohols, ethers or esters.

~48%

~68%

~50%

~82%

~87%

~88%

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