Electrochemistry of NADH/NAD+ analogs. A detailed mechanistic kinetic and thermodynamic analysis of the 10-methylacridan/10-methylacridinium couple in …

P Hapiot, J Moiroux, JM Saveant

文献索引：Hapiot, Philippe; Moiroux, Jacques; Saveant, Jean-Michel Journal of the American Chemical Society, 1990 , vol. 112, # 4 p. 1337 - 1343

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被引用次数: 104

摘要

Conclusions STM results reported here demonstrate that the chemical composition and structure of [Re (CO),(vbpy) Cl]-based films are remarkably dependent on conditions employed in electrodeposition. Polymeric materials with several different morphologies are observed when the deposition is carried out to-1.45 V vs SSCE. A more uniform surface coverage of discrete molecules is observed when the potential is scanned to-2.0 V to ...