Cyclopropanol derivatives as intermediates for organochemical synthesis

E Wenkert, RA Mueller, EJ Reardon Jr…

文献索引：Wenkert,E. et al. Journal of the American Chemical Society, 1970 , vol. 92, p. 7428 - 7436

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被引用次数: 77

摘要

Abstract: A design of terpene synthesis based on the acid-induced transformations of cyclopropyl ethers and p-methoxycyclopropylcarbinols into quaternary a-methyl and a-vinyl carbonyl compounds, respectively, is described. Similar reactions with gem- dimethoxycyclopropanes are portrayed. A cyclopropylamine is shown to be inert. p- Methoxycyclopropanecarboxylic esters are converted into y-ketocarboxylic acid ...