Synthesis of glyceryl ethers in high optical purity via ruthenium catalyzed asymmetric hydrogenation

E Cesarotti, A Mauri, M Pallavicini, L Villa

文献索引：Cesarotti, Edoardo; Mauri, Angela; Pallavicini, Marco; Villa, Luigi Tetrahedron Letters, 1991 , vol. 32, # 34 p. 4381 - 4384

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被引用次数: 24

摘要

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... 1-O-octadecyl-3-O-trityl-glycerol and 1-O-benzyl-3-O-trityl-glycerol can be prepared by asymmetric catalytic hydrogenation in OP> 96% and 87–88% respectively. ... 4a: 1 H NMR (80MHz, CDCl 3 ) δ : 7.6-7.2 (m, 15H), 4.3 (s, 2H), 3.9 (s, 2H), 3.4 (br.t, 2H), 1.3 (br.s ,32H), 0.9(br.t, 3H); ...