Reaction of ozonide with antimony pentachloride or chlorosulfuric acid. Participation of antimony pentachloride-complexed or protonated carbonyl oxide

M Miura, M Nojima

文献索引：Miura,M.; Nojima,M. Journal of the American Chemical Society, 1980 , vol. 102, p. 288

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被引用次数: 17

摘要

Abstract: The reactions of 1 1 kinds of 1, 2, 4-trioxolanes (ozonides) with SbCIS or CIS03H in methylene chloride have been investigated. Depending on the substituents, the reaction paths seem to vary. We have proposed the mechanism that heterolytic fission of the C-0 bond of the peroxide bridge affords 3, 6-dialkyl-1, 2, 4, 5-tetroxane and/or 1, 4-dialkyl-2, 3, 5, 6, 1 I-pentaoxabicyclo [5.3. Ilundecane. The reaction of methylcyclopentene ozonide with ...