Synthesis and properties of fluorosilicon-containing polybutadienes by hydrosilylation of fluorinated hydrogenosilanes. Part 1. Preparation of the silylation agents

B Ameduri, B Boutevin, M Nouiri, M Talbi

文献索引：Ameduri, B.; Boutevin, B.; Nouiri, M.; Talbi, M. Journal of Fluorine Chemistry, 1995 , vol. 74, # 2 p. 191 - 198

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被引用次数: 35

摘要

The synthesis of new fluorinated hydrogenosilanes CnF2n+ 1 (CH2) xC2H4Si (CH3) 2H with n= 6 or 8 and x= 0 or 1 is presented. Such compounds were prepared in 85%–90% yield by the selective reduction of the corresponding fluorine-containing (dimethyl) chlorosilanes. These chlorinated derivatives were produced by the hydrosilylation of (dimethyl) chlorosilane with perfluoroalkylvinyl, CnF2n+ 1CH CH2 (x= 0), or allyl, ...