Synlett

Novel and unexpected deamination during the palladium-catalysed cross-coupling of haloanilines and arylboronic acids

M Hird, AJ Seed, KJ Toyne

文献索引：Hird, Michael; Seed, Alexander J.; Toyne, Kenneth J. Synlett, 1999 , # 4 p. 438 - 440

被引用次数: 10

摘要

Abstract: Palladium-catalysed cross-coupling reactions involving haloanilines and arylboronic acids produce the expected biaryl products, but additionally a substantial quantity of the corresponding deaminated biaryl is also generated which constitutes a novel synthetic methodology. Key words: deamination, palladium-catalysed, cross-coupling, arylboronic acids

~39%

121219-12-3

4-正戊基苯硼酸

~45%

~33%

~41%

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