Palladium (II)-catalyzed asymmetric oxidative cyclization of 2-allylphenols in the presence of copper (II) acetate and molecular oxygen. Study of the catalysis of the …

T Hosokawa, T Uno, S Inui…

文献索引：Hosokawa, Takahiro; Uno, Tetsuyuki; Inui, Shiro; Murahashi, Shun-Ichi Journal of the American Chemical Society, 1981 , vol. 103, # 9 p. 2318 - 2323

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被引用次数: 172

摘要

Results Catalytic Reaction of trans-2-(2-Butenyl) phenol. The chiral catalyst,(+)-(~ 3-pinene) palladium (II) acetate (l), employed for the present study was prepared by treatment of the corresponding chloride complex with AgOAc. The chloride complex was synthesized by the reaction of (-)-&pinene and Pd (OAc) 2 followed by addition of NaCI. 15