Aromatic annelation by reaction of arylimidoyl radicals with alkynes: a new synthesis of quinolines

R Leardini, GF Pedulli, A Tundo…

文献索引：Leardini, Rino; Pedulli, Gian Franco; Tundo, Antonio; Zanardi, Giuseppe Journal of the Chemical Society, Chemical Communications, 1984 , # 20 p. 1320 - 1321

全文：HTML全文

被引用次数: 30

摘要

An easily effected aromatic annelation is described, involving the reaction of arylimidoyl radicals with alkynes to give qui no1 ines. ~ Imidoyl radicals have been investigated by esr spectroscopy by several workers and the spectroscopic results have been rationalized on the assumption that they possess a a-electronic configuration. 1 However, the chemical reactivity of these radicals and their use as intermediates for organic syntheses have so far received little attention. ...