Synthesis of 4, 6-dideoxyfuranoses through the regioselective and diastereoselective oxyfunctionalization of a dimethylphenylsilyl-substituted chiral homoallylic …
W Adam, CR Saha-Möller…
文献索引:Adam, Waldemar; Prechtl, Frank; Richter, Markus J.; Smerz, Alexander K. Tetrahedron Letters, 1995 , vol. 36, # 28 p. 4991 - 4994
The 4, 6-dideoxyfuranoses 10a and 10b have been synthesized by starting from the readily available E-5-dimethylphenylsilyl-2-hexene-4-ol (1) and employing successively three versatile oxyfunctionalization methods, namely photooxygenation, metal-catalyzed