Iminophosphorane-mediated transformation of tertiary alcohols into t-alkylamines and their N-phosphorylated derivatives

A Koziara, A Zwierzak

文献索引：Koziara, Anna; Zwierzak, Andrzej Tetrahedron Letters, 1987 , vol. 28, # 51 p. 6513 - 6516

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被引用次数: 26

摘要

Abstract Novel azidation of tertiary alcohols by means of trimetylsilyl azide in the presence of boron trifluoride etherate has been worked out. The Staudinger reaction of crude azides with triethyl phosphite affords the corresponding iminophosphoranes which can be directly transformed into diethyl N-(t-alkyl) phosphoroamidates or t-alkylamine tosylates.