Tetrahedron

Water works: an efficient palladium-catalyzed cross-coupling reaction between boronic acids and bromoacetate with aminophosphine ligand

ZY Peng, JP Wang, J Cheng, X Xie, Z Zhang

文献索引：Peng, Zhi-Yong; Wang, Jian-Ping; Cheng, Jiang; Xie, Xiao-Min; Zhang, Zhaoguo Tetrahedron, 2010 , vol. 66, # 42 p. 8238 - 8241

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被引用次数: 11

摘要

There are two general reaction pathways to realize the arylation of corresponding esters to generate α-aryl carboxylic acid derivatives reported by transition metal-catalyzed reactions (Scheme 1). Reactions via pathway (i), which involves a palladium-catalyzed coupling reaction between aryl halide electrophiles and enolates, were extensively studied by Buchwald 2, 2a, 2b, 2c, 2d, 2e and 2f and Hartwig. 3, 3a, 3b, 3c and 3d In these reactions, bulky, electron-rich ...

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