Coordination, heterolysis, and electron-transfer reactions involving delocalized carbocations and carbanions in solution

EB Troughton, KE Molter, EM Arnett

文献索引：Troughton,E.B.; Molter,K.E.; Arnett,E.M. Journal of the American Chemical Society, 1984 , vol. 106, p. 6726

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被引用次数: 55

摘要

Abstract: The effect of structure and reaction conditions on carbon-carbon bond formation was investigated by the direct reaction of resonance-stabilized carbocations and carbanions in solution. Preliminary results indicated rates of coordination that range from diffusion controlled for the least stable ions to a total lack of reaction for the most stable ones after months of standing at room temperature. These results suggested that coordination/ ...