The addition of fluorine to halogenated olefins by means of metal fluorides

DA Rausch, RA Davis, DW Osborne

文献索引：Rausch,D.A. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 494 - 497

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被引用次数: 14

摘要

The selective addition of fluorine to the double bond of olefins by means of vapor phase reaction with cobalt trifluoride at 20-125'has been found to be quite general for stable halogenated olefins. Chloroethylene, cis-1, 2 dichloroethylene, trichloroethylene, 1, l- difluoroethylene, 2-bromo-l, l, l-trifluoropropene, and 2-fluoropropene produced the respective vicinal difluoro derivatives in fair yields. In addition, compounds produced by ...