C X (X= Br, I) Bond??Tolerant Aerobic Oxidative Cross??Coupling: A Strategy to Selectively Construct β??Aryl Ketones and Aldehydes

M Chen, J Wang, Z Chai, C You…

文献索引：Chen, Mao; Wang, Jie; Chai, Ziyi; You, Cai; Lei, Aiwen Advanced Synthesis and Catalysis, 2012 , vol. 354, # 2-3 p. 341 - 346

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被引用次数: 17

摘要

Abstract Using moelcular oxygen as the terminal oxidant, various aryl halide-containing β- aryl ketones and aldehydes can be synthesized directly from readily available allyic alcohols and boronic acids via palladium-catalyzed oxidative cross-coupling reactions. The dual roles of copper, including electron-carrier and Lewis acid functions, are supposed to be critical for the high reactivity and selectivity of this aerobic oxidative coupling ...