Demonstration of the facile reversibility of fulvene formation

JS Bandar, RW Coscia, TH Lambert

文献索引：Bandar, Jeffrey S.; Coscia, Rockford W.; Lambert, Tristan H. Tetrahedron, 2011 , vol. 67, # 24 p. 4364 - 4370

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被引用次数: 2

摘要

Abstract Cleavage of fulvenes under mild conditions and interchange between electron- deficient fulvenes and their constituent cyclopentadienes and imines is demonstrated for the first time. A series of cyclopentadienes and imines are investigated to probe the dependence of fulvene equilibration on structure. The exchange of one fulvene for another is demonstrated in the first reported example of transfulvenation. Finally, the metathesis of ...