Direct substitution of the hydroxy group in alcohols with silyl nucleophiles catalyzed by indium trichloride

M Yasuda, T Saito, M Ueba…

Index: Yasuda, Makoto; Saito, Takahiro; Ueba, Masako; Baba, Akio Angewandte Chemie - International Edition, 2004 , vol. 43, # 11 p. 1414 - 1416

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Citation Number: 112

Abstract

15 2l 180 3l 59 16 [d, e] 2m 60 3m 56 [a] The reactions were carried out in dichloromethane (1 mL) with allylsilane 1 (2.0 mmol), alcohol 2 (1.0 mmol), and InCl3 (0.05 mmol) at RT unless otherwise stated.[b] Allylsilane 1 (3.0 mmol), dichloromethane (2 mL).[c] Allylsilane 1 (3.0 mmol), dichloroethane (2 mL), 808C.[d] Allylsilane 1 (4.0 mmol).[e] Bu4NF was added during the workup.