Syntheses of Organic N, N-Dialkyldithiocarbamates or Organic Thiocyanates from Organozincs and Corresponding Thio-Anions via the Inversion of Electronic …

K Takagi, H Takachi, K Sasaki

Index: Takagi, Kentaro; Takachi, Hideaki; Sasaki, Ken Journal of Organic Chemistry, 1995 , vol. 60, # 20 p. 6552 - 6556

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Citation Number: 14

Abstract

Novel displacement of metal ions from organometallic compounds with nucleophilic reagents was achieved in the reaction between organozinc compounds and NJV- dialkyldithiocarbamate ions (NJV-DAD-) or thiocyanate ion by the assistance of NCS, whereby alkyl or aryl NJV-DAD or alkyl, alkenyl, alkynyl, aryl, or heteroaryl thiocyanates were obtained in moderate to excellent yields as the result of novel bond construction ...