ChemicalBook CAS DataBase List 2-Allyloxy-1,3,5-tribromobenzene

2-Allyloxy-1,3,5-tribromobenzene synthesis

5synthesis methods

Product Name:2-Allyloxy-1,3,5-tribromobenzene
CAS Number:3278-89-5
Molecular formula:C9H7Br3O
Molecular Weight:370.86

To the ethanol solution of the sodium tribromophenolate salt prepared in the step 1), the dispersing agent sodium stearate 2.5 g is added.And catalyst II phenyl triethyl ammonium chloride 5.6g,The temperature is raised to 75 ° C to reflux the reaction.Further, 1000 ml of an ethanol solution of chloropropene having a volume ratio of chloropropene to ethanol of 1:5 was slowly added thereto, and then the reaction was kept at 75 ° C for 6.5 h until the end.Then, the temperature is lowered to 7 ° C in sequence, and then suction filtration is performed to recover the ethanol solution.After washing the filter cake with water, the filter cake was dried at 60 ° C.2,4,6-Tribromophenyl allyl ether was obtained as a white powdery solid in a yield of 96.2%.

2666-53-7 Synthesis

2666-53-7
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107-05-1 Synthesis

107-05-1
426 suppliers
$16.80/100ML

3278-89-5
78 suppliers
$48.40/250g

Yield: 96.2%

Reaction Conditions:

with sodium stearate;benzyltriethylammonium chloride in ethanol at 75; for 6.5 h;Reagent/catalyst;Temperature;

Steps:

1.1; 2.1; 3.1; 4.1; 5.1 2) Synthesis of 2,4,6-tribromophenyl allyl ether:
To the ethanol solution of the sodium tribromophenolate salt prepared in the step 1), the dispersing agent sodium stearate 2.5 g is added.And catalyst II phenyl triethyl ammonium chloride 5.6g,The temperature is raised to 75 ° C to reflux the reaction.Further, 1000 ml of an ethanol solution of chloropropene having a volume ratio of chloropropene to ethanol of 1:5 was slowly added thereto, and then the reaction was kept at 75 ° C for 6.5 h until the end.Then, the temperature is lowered to 7 ° C in sequence, and then suction filtration is performed to recover the ethanol solution.After washing the filter cake with water, the filter cake was dried at 60 ° C.2,4,6-Tribromophenyl allyl ether was obtained as a white powdery solid in a yield of 96.2%.

References:

Shandong Runke Chemical Co., Ltd.;Weifang Yucheng Chemical Co., Ltd.;Wu Duokun;Wang Dongquan;Qin Shanbao;Zhang Junying;Yang Lili CN109053389, 2018, A Location in patent:Page/Page column 4-6

106-95-6 Synthesis