Syntheses of a new tripodal alane/tris(phosphine) ligand (AlP₃) based on 2-(diisopropylphosphino)pyrrole, and AlP₃-supported Ni complexes are reported. The central tris(pyrrolyl)aluminum moiety acts as a stronger Lewis acid towards Ni than other related group 13 element-centered tripodal ligands, as demonstrated by the binding of H₂ to Ni and the ease of reduction.