| Identification | More | [Name]
N-Methyl-4-nitroaniline | [CAS]
100-15-2 | [Synonyms]
4-METHYLAMINONITROBENZENE
4-nitro-n-methylaniline
N-METHYL-4-NITROANILINE
N-METHYL-P-NITROANILINE
P-NITRO-N-METHYLANILINE
Aniline, N-methyl-p-nitro-
Benzenamine,N-methyl-4-nitro-
n-methyl-4-nitro-benzenamin
N-methyl-4-nitro-Benzenamine
N-Methyl-N-(4-nitrophenyl)amine
N-Methyl-p-nitraniline
N-Monomethyl-p-nitroaniline
p-(Methylamino)nitrobenzene
N1-methyl-4-nitroaniline
N-METHYL-4-NITRO ANILIN
1-METHYLAMINO-4-NITROBENZENE
Nitronaniline
N-Methyl-4-nitroaniline ,99% | [EINECS(EC#)]
202-823-2 | [Molecular Formula]
C7H8N2O2 | [MDL Number]
MFCD00007305 | [Molecular Weight]
152.15 | [MOL File]
100-15-2.mol |
| Chemical Properties | Back Directory | [Appearance]
brownish-yellow crystalline powder | [Melting point ]
149-151 °C(lit.)
| [Boiling point ]
294.61°C (rough estimate) | [density ]
1.2010 | [vapor density ]
5.25 (vs air)
| [refractive index ]
1.6276 (estimate) | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
0.56±0.12(Predicted) | [color ]
Yellow to Very Dark Yellow | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents. | [Water Solubility ]
<0.1 g/100 mL at 19 ºC | [Detection Methods]
HPLC,NMR | [BRN ]
637920 | [InChIKey]
XIFJZJPMHNUGRA-UHFFFAOYSA-N | [CAS DataBase Reference]
100-15-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzenamine, N-methyl-4-nitro-(100-15-2) | [EPA Substance Registry System]
100-15-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T,Xi | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R33:Danger of cumulative effects.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
2811 | [WGK Germany ]
3
| [Hazard Note ]
Highly Toxic/Irritant | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29214200 |
| Hazard Information | Back Directory | [General Description]
Brownish-yellow prisms with violet reflex (from ethanol) or yellow powder. | [Reactivity Profile]
N-METHYL-4-NITROANILINE(100-15-2) has a vigorous exothermic reaction with carbaryl sulfate when heated above 167° F. | [Air & Water Reactions]
This chemical may be sensitive to prolonged exposure to air. Insoluble in water. | [Fire Hazard]
Flash point data for this chemical are not available; however, N-METHYL-4-NITROANILINE is probably combustible. | [Chemical Properties]
brownish-yellow crystalline powder | [Purification Methods]
Crystallise the aniline from aqueous EtOH. [Beilstein 12 H 714.] |
| Questions And Answer | Back Directory | [Biodegradation]
N-Methyl-4-nitroaniline is used as an additive to lower the melting temperature of energetic materials in the synthesis of insensitive explosives. Although the biotransformation of N-Methyl-4-nitroaniline under anaerobic condition has been reported, its aerobic microbial degradation has not been documented yet. A soil microcosms study showed the efficient aerobic degradation of N-Methyl-4-nitroaniline by the inhabitant soil microorganisms.
| [Uses]
N-methyl-4-nitroaniline is a stabilizer for gunpowder, a desensitizing agent for molten cast explosive TNAZ, a widely used organic intermediate, and N-methyl-4-nitroaniline can be used as a reference substance by its polarizing properties.
N-methyl-4-nitroaniline is an attractive candidate for its appealing capability to retain the nitrogen oxides, good thermal stability, and facile synthesis from abundant and inexpensive starting materials.
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