| Identification | More |  [Name]
  3-Methyl-4-anisaldehyde |  [CAS]
  32723-67-4 |  [Synonyms]
  3-METHYLANISALDEHYDE 3-METHYL-P-ANISALDEHYDE 4-METHOXY-3-METHYLBENZALDEHYDE 4-METHOXY-M-TOLUALDEHYDE ASISCHEM R37628 TIMTEC-BB SBB008533 3-Methyl-para-anisaldehyde Benzaldehyde, 4-methoxy-3-methyl- 3-methyl-4-anisaldehyde 3-Methyl-p-anisaldehyde (CHO=1) 4-METHOXY-M-TOLUALDEHYDE---LIQUID, D29 1.09, N20 1.569--- 3-Methyl-4-methoxybenzaldehyde 4-Methoxy-3-tolualdehyde |  [EINECS(EC#)]
  251-177-8 |  [Molecular Formula]
  C9H10O2 |  [MDL Number]
  MFCD00003375 |  [Molecular Weight]
  150.17 |  [MOL File]
  32723-67-4.mol |  
 | Chemical Properties | Back Directory |  [Appearance]
  Clear pale yellow to green liquid |  [Boiling point ]
  80-85 °C/1 mmHg (lit.) |  [density ]
  1.098 g/mL at 20 °C(lit.) 
 |  [refractive index ]
  n20/D 1.569 
 |  [Fp ]
  234 °F 
 |  [storage temp. ]
  Keep in dark place,Sealed in dry,Room Temperature |  [solubility ]
  Chloroform, Ethyl Acetate |  [form ]
  Oil |  [color ]
  Clear Colorless |  [Specific Gravity]
  1.025 |  [Odor]
  Sweet-balsamic, earthy-floral odor of considerable tenacity |  [BRN ]
  2084045 |  [CAS DataBase Reference]
  32723-67-4(CAS DataBase Reference) |  [NIST Chemistry Reference]
  3-Methyl-p-anisaldehyde(32723-67-4) |  
 | Safety Data | Back Directory |  [Safety Statements ]
  S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . S24/25:Avoid contact with skin and eyes . |  [WGK Germany ]
  3 
 |  [HazardClass ]
  IRRITANT |  [HS Code ]
  29124990 |  
 | Hazard Information | Back Directory |  [Chemical Properties]
  Clear pale yellow to green liquid |  [Uses]
 
 4-Methoxy-3-methylbenzaldehyde was used in the preparation of (4-methoxy-3-methylphenyl)-2-nitroalkene.  |  [Synthesis Reference(s)]
  The Journal of Organic Chemistry, 49, p. 1078, 1984 DOI: 10.1021/jo00180a024 |  [Synthesis]
  3-Methyl-4-anisaldehyde is prepared by Diazoreaction upon 4-Amino-3-methylbenzaldehyde, followed by Methylation with Dimethyl sulfate in weak
aqueous alkali. |  [References]
  [1] Beilstein Journal of Organic Chemistry,  2018,  vol. 14,  p. 734 - 746 |  
  
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