| Identification | More | [Name]
1-Butaneboronic acid | [CAS]
4426-47-5 | [Synonyms]
1-BUTANEBORONIC ACID
1-BUTYLBORONIC ACID
1-(dihydroxyboryl)butane
BUTYLBORIC ACID
BUTYLBORONIC ACID
NBBA
N-BUTANEBORONIC ACID
N-BUTYLBORONIC ACID
1-butyldihydroxyborane
BUTYLBORONIC ACID, FOR GC
BURYLBORONIC ACID
N-ButylboronicAci
n-Butylboronicacid,96%
N-Butylboronic
Boronic acid, butyl-
butyl boron dihydroxide
Butylboronic Acid (contains varying amounts of Anhydride) [for Esterification]
Butyldihydroxyborane
Butylboranic acid
Butylboron dihydoxide | [EINECS(EC#)]
224-607-7 | [Molecular Formula]
C4H11BO2 | [MDL Number]
MFCD00002106 | [Molecular Weight]
101.94 | [MOL File]
4426-47-5.mol |
| Chemical Properties | Back Directory | [Appearance]
white to faintly beige shinying platelets | [Melting point ]
90-92 °C(lit.) | [Boiling point ]
189.2±23.0 °C(Predicted) | [density ]
1.022 g/cm3 | [storage temp. ]
0-6°C | [solubility ]
DMSO (Slightly), Methanol (Slightly) | [form ]
Liquid | [pka]
10.37±0.43(Predicted) | [color ]
Clear colorless to slightly yellow | [Water Solubility ]
ca 2.5 g/100 mL | [Sensitive ]
Air Sensitive & Hygroscopic | [BRN ]
1733489 | [InChI]
InChI=1S/C4H11BO2/c1-3-4(2)5(6)7/h4,6-7H,3H2,1-2H3 | [InChIKey]
QPKFVRWIISEVCW-UHFFFAOYSA-N | [SMILES]
CC(B(O)O)CC | [CAS DataBase Reference]
4426-47-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [F ]
3-10-23 | [TSCA ]
No | [HazardClass ]
IRRITANT | [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Chemical Properties]
white to faintly beige shinying platelets | [Uses]
1-Butylboronic acid is used as a reagent for preparation of volatile derivatives of diols, e.g. carbohydrates, for GC and mass spectrometry and to prepare chiral oxazaborolidines. It is a precursor to unsymmetric borinic acids, which are inhibitors of serine proteases. Can be used as a transport carrier in membrane-based sugar separations and as an analytical reagent in the determination of serum glucose. | [Uses]
n-Butylboronic acid can be used in suzuki reaction.
| [Uses]
n-Butylboronic acid is a boronic acid derivative that can be used as a transport carriers in membrane-based sugar separations. n-Butylboronic acid is used as an analytical reagent in the determination of serum glucose.
| [reaction suitability]
reagent type: derivatization reagent
reaction type: Alkylations | [Purification Methods]
Butylboronic acid (1-butanedihydroxyborane) [4426-47-5] M 101.9, m 90 -92o, 94 -96o, pKEst ~8.8.acuo. [Corey et al. J Am Chem Soc 116 3151 1994, Quallich et al. J Am Chem Soc 116 8515 1994, Seerden Tetrahedron Lett 35 4419 1994, Beilstein 4 IV 4383.] |
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