Bis(acetonitrile)dichloropalladium(II)
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Bis(acetonitrile)dichloropalladium(II) 속성
- 녹는점
- 300 °C
- 저장 조건
- Inert atmosphere,Room Temperature
- 용해도
- 아세토니트릴, 아세톤, 클로로포름에 용해됨
- 물리적 상태
- 미세 결정성 분말
- 색상
- 주황색에서 녹갈색까지
- 수용성
- 불용성
- InChI
- InChI=1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2
- InChIKey
- RBYGDVHOECIAFC-UHFFFAOYSA-L
- SMILES
- C(#N)C.C(#N)C.[Pd](Cl)Cl
- CAS 데이터베이스
- 14592-56-4(CAS DataBase Reference)
안전
- 위험 및 안전 성명
| 위험품 표기 | T,Xn | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 23/24/25-36/37/38-20/21/22 | ||
| 안전지침서 | 16-27-36/37-45-36-26 | ||
| 유엔번호(UN No.) | UN 3077 9/PG 3 | ||
| WGK 독일 | 3 | ||
| TSCA | No | ||
| 위험 등급 | 6.1 | ||
| 포장분류 | III | ||
| HS 번호 | 28439090 |
Bis(acetonitrile)dichloropalladium(II) C화학적 특성, 용도, 생산
화학적 성질
Light yellow to Brown powder to crystaline.물리적 성질
Bis(acetonitrile)dichloropalladium(II) is a yellow-brown solid that is soluble in organic solvents. It is a reagent and a catalyst for reactions that require soluble Pd(II).The compound is similar to bis(benzonitrile)palladium dichloride.용도
suzuki reaction제조 방법
Bis(acetonitrile)palladium dichloride is prepared by reacting two acetonitrile ligands and palladium(II) chloride.주요 응용
Synthesis of Oxindoles
To a dried screw-cap vial is added anilide (0.3 mmol), AgOCOCF3 (132.5 mg, 0.6 mmol), Bis(acetonitrile)dichloropalladium(II) (3.5 mg, 0.015 mmol) and chlorobenzene. The reaction mixture is stirred at 100-120 °C for 3-12 h in a pre-heated oil bath. After cooling to room temperature, the reaction is diluted with EtOAc and filtered with a glass filter. The filtrate is washed with 5% aqueous NaHCO3 and brine. The extract is dried over MgSO4 and concentrated in vacuo. The crude is purified by preparative TLC.
일반 설명
This product has been enhanced for catalytic efficiency.Bis(acetonitrile)dichloropalladium(II) 준비 용품 및 원자재
원자재
준비 용품
Bis(acetonitrile)dichloropalladium(II) 공급 업체
글로벌( 380)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Wuhan Huahan Dingcheng New Material Technology Co., Ltd | +undefined-027-81388558 +undefined086-1878077615 |
huahandingcheng@sina.com | China | 342 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615350571055 |
Sibel@chuanghaibio.com | China | 8768 | 58 |
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-13017695106 +86-13676922317 |
jiuyitime@fdachem.com | China | 16514 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 |
sales@capot.com | China | 29735 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21614 | 55 |
| AB PharmaTech,LLC | 323-480-4688 |
sales@acrospharmatech.com | United States | 989 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29847 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 |
info@accelachem.com | United States | 21193 | 58 |
| Yunbio Tech Co.,Ltd. | +86-010-60605551 +86-18046518538 |
yunbiochem@126.com | China | 321 | 58 |
Bis(acetonitrile)dichloropalladium(II) 관련 검색:
디메틸에틸렌디아민 BIS(DI-TERT-BUTYLPHOSPHINO)메탄 디클로로비스(디-tert-부틸페닐포스핀)팔라듐(II) BIS(N-PROPYLCYCLOPENTADIENYL)마그네슘 BIS(I-프로필사이클로펜타디에닐)망간 BIS(펜타메틸사이클로펜타디에닐)마그네슘 BIS(I-프로필사이클로펜타디에닐)이염화티타늄 비스(에틸사이클로펜타디닐)니켈 비스(펜타메틸사이클로펜타디에닐)니켈 디클로로비스(메틸디페닐포스핀)팔라듐(II) [비스(트리플루오로아세톡시)요오도]벤젠 비스(디페닐포스피노페닐)에테르팔라듐(II)디클로라이드 디클로로비스(클로로디-tert-부틸포스핀)팔라듐(II) 비스[트리스(2-메틸페닐)포스핀]팔라듐 팔라듐 디클로로 비스 (벤조 니트릴) 팔라듐 (II) 팔라듐 염화물
TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II)