|
|
| | ISOPROPENYLMAGNESIUM BROMIDE Basic information |
| Product Name: | ISOPROPENYLMAGNESIUM BROMIDE | | Synonyms: | Isopropenylmagnesium bromide, 0.5 M solution in THF, HySeal;ISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURAN;ISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURAN;ISOPROPENYLMAGNESIUM BROMIDE 0.5 M THF;Isopropenylmagnesium bromide( 1.0 M solution in THF);IsopropenyL;Isopropenylmagnesium bromide 1M solution in tetrahydrofuran;ISOPROPENYLMAGNESIUM BROMIDE | | CAS: | 13291-18-4 | | MF: | C3H5BrMg | | MW: | 145.28 | | EINECS: | 603-688-6 | | Product Categories: | Grignard Reagent;Alkenyl;Grignard Reagents;Organometallic Reagents | | Mol File: | 13291-18-4.mol |  |
| | ISOPROPENYLMAGNESIUM BROMIDE Chemical Properties |
| Melting point | 102-104 °C | | Boiling point | 67 °C | | density | 0.94 g/mL at 20 °C | | Fp | −36 °F | | storage temp. | 2-8°C | | form | Crystalline Powder | | color | White to yellow to orange | | BRN | 3587297 | | InChI | InChI=1S/C3H5.BrH.Mg/c1-3-2;;/h1H2,2H3;1H;/q;;+1/p-1 | | InChIKey | LFTYALBVGVNGLI-UHFFFAOYSA-M | | SMILES | C(=C)(C)[Mg]Br |
| Hazard Codes | F,C | | Risk Statements | 11-14/15-34-40-37-19-14 | | Safety Statements | 26-30-36/37/39-43-45-7/8-16 | | RIDADR | UN 3399 4.3/PG 1 | | WGK Germany | 1 | | F | 1-3-10-34 | | HS Code | 29319090 | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
Water-react 1 |
| | ISOPROPENYLMAGNESIUM BROMIDE Usage And Synthesis |
| Uses | Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry | | Uses | Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-()-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol. | | General Description | This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. | | reaction suitability | reaction type: Grignard Reaction | | Synthesis | The Preparative Method of 2-Propenylmagnesium Bromide-Copper(I) Iodide: prepared in situ under anhydrous conditions by reacting 2-propenylmagnesium bromide (1) with Copper(I) Iodide (2) in varying molar ratios.
|
| | ISOPROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials |
|