102-51-2 (4-甲基邻苯二胺,3,4-Diaminoanisole)

快速询单

结构式：

4-甲基邻苯二胺MOL文件

CAS号：

102-51-2

中文名称：

4-甲基邻苯二胺

英文名称：

3,4-Diaminoanisole

分子式：

C₇H₁₀N₂O

分子量：

138.167101383209

4-甲基邻苯二胺(102-51-2)名称与标识符

名称

中文别名：

4-甲基邻苯二胺;4-甲氧基邻苯二胺;3,4-二氨基苯甲醚;1,2-二氨基-4-甲氧基苯 4-甲氧基-1,2-苯二胺;2-氨基-4-甲氧基苯胺;4-（3-丙氨基）-1,3-噻唑-2-氨基;4-甲氧基苯基-1,2-二胺;对甲氧基邻苯二胺;4-甲氧基-1,2-苯二胺;4-甲氧基邻基苯二胺;4-甲氧基邻亚苯基二胺;2-氨基-4-甲氧苯基胺;4-甲氧基苯-1,2-二胺;4-甲氧基-邻-伸苯基二胺;4-甲氧基邻苯二胺 1G;4-甲氧基邻苯二胺,98%;埃索美拉唑杂质25;

英文别名：

3,4-Diaminoanisole;Methoxyophenylenediamine;4-methoxybenzene-1,2-diamine;4-Methoxy-O-Phenylenediamine;2-Amino-4-methoxyphenylamine;4-methoxy-1,2-Benzenediamine;4-methoxy-2-benzenediamine;4-Methoxy-1,2-phenylenediamine;3,4-Diaminoanisidine;2-Amino-4-methoxy aniline;4-Methoxy-1,2-diaminobenzene;4-Methoxy-2-aMinoaniline;2-DiaMino-4-Methoxybenzene;4-methoxy-o-phenylenediamin;1,2-Diamino-4-methoxybenzene;3,4-DIAMINO ANISOLE;1,2-Benzenediamine, 4-methoxy-;o-Phenylenediamine, 4-methoxy-;1,2-Benzenediamine, 4-methoxy- (9CI);1,2-Benzenediamine,4-methoxy-;AGAHETWGCFCMDK-UHFFFAOYSA-N;4-METHOXY-PHENYLENEDIAMINE;4-Methoxy-benzene-1,2-diamine;3,4 diam;4-Methoxy-1,2-benzenediamine #;FT-0618911;M2882;SCHEMBL234263;AC-26078;MFCD00047837;102-51-2;NS00023156;3,4-Diaminoanisole;1,2-Benzenediamine,4-methoxy;4-Methoxy-1,2-benzenediamine;4-methoxy-o-phenylene diamine;57B24QB262;BB 0241897;AKOS000103845;BRN 0878789;p-Methoxy-o-phenylenediamine;EN300-85295;AMY10750;Omeprazole Impurity 2;5-methoxy-o-phenylenediamine;BCP30876;3,4 diamino anisole;J-000710;CS-W001175;SY032808;Q63391608;AB02069;A20812;DTXSID00144514;1,2-diamino-4-methoxy-benzene;NCIOpen2_003403;STR02678;STK500752;aniline, 2-amino-4-methoxy-;ALBB-006147;4-Methoxybenzene-1,2-diamine;;

标识符

MDL：

MFCD00047837

InChIKey：

AGAHETWGCFCMDK-UHFFFAOYSA-N

Inchi：

1S/C7H10N2O/c1-10-5-2-3-6(8)7(9)4-5/h2-4H,8-9H2,1H3

SMILES：

O(C)C1C=CC(=C(C=1)N)N

BRN：

0878789

4-甲基邻苯二胺(102-51-2)物化性质

实验特性

LogP : 2.02200
PSA : 61.27000
折射率 : 1.5200 (estimate)
沸点 : 302.4°C at 760 mmHg
熔点 : 130-131.5 ºC
蒸气压 : 0.0±0.6 mmHg at 25°C
闪点 : 161.7°C
溶解度 : 微溶 (8.2 g/L) (25 ºC),
颜色与性状 : 绿色片状结晶
溶解性 : 溶于乙醚
敏感性 : Air Sensitive
密度 : 1.170±0.06 g/cm3 (20 ºC 760 Torr),

计算特性

精确分子量 : 138.07900
氢键供体数量 : 2
氢键受体数量 : 3
可旋转化学键数量 : 1
同位素质量 : 138.079
重原子数量 : 10
复杂度 : 108
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 0.6
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 61.3

4-甲基邻苯二胺(102-51-2)安全信息

RTECS号： ST2690000
安全术语： S26-S36/37/39-S45
安全说明： S26; S36/37/39; S45
风险术语： R23/24/25
危险品标志： Xi
危险品运输编号： 2811
危害声明：H302+H312+H332-H315-H319-H335
警示性声明：P261; P264; P271; P280; P302+P352; P304+P340; P305+P351+P338; P312; P321; P332+P313; P337+P313; P362; P403+P233; P405; P501
储存条件： Keep in dark place,Inert atmosphere,2-8°C
PackingGroup： III
危险类别码： 23/24/25-36/37/38
信号词： Warning
HazardClass： 6.1

4-甲基邻苯二胺(102-51-2)国际标准相关数据

EINECS：

4-甲基邻苯二胺(102-51-2)海关数据

海关编码：

2922299090

海关数据：

中国海关编码：

2922299090

概述：

2922299090. 其他氨基(萘酚、酚)及醚、酯〔包括它们的盐, 但含有一种以上含氧基的除外〕. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

申报要素：

品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

Summary：

2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

4-甲基邻苯二胺(102-51-2)推荐厂家更多厂家(65)

公司名称	手机号/电话	联系人	QQ	询单
北京华威锐科化工有限公司	13269663372 010-89508211	李爽	2853391965	询单
湖北摆渡化学有限公司	18871490324 027-59106051	彭星	1400878899	询单
上海吉至生化科技有限公司	18117592386 021-57481218	吉至试剂	3007522982	询单
深圳菲斯生物科技有限公司	18925202235	周美娇	2850179284	询单
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湖北方德新材料有限公司	18086096695	邱经理	1462312301	询单
湖北扬信医药科技有限公司	13092795037 0714-3996388	熊磊	3003473323	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
湖北诺纳科技有限公司	18995657604 027-59209883	吴经理	2933307129	询单
湖北巨胜科技有限公司	18871490354	王珊	1400848866	询单

4-甲基邻苯二胺(102-51-2)上下游

2-羟甲基-5-甲氧基苯并咪唑 5-甲基-1H-茚 5-甲氧基苯并咪唑 5-甲氧基-2-甲基苯并咪唑 (9ci)-5-甲氧基-1-甲基-1H-苯并咪唑-2-羧醛

4-甲基邻苯二胺(102-51-2)相关文献

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10. Nickel-catalysed dehydrogenative coupling of aromatic diamines with alcohols: selective synthesis of substituted benzimidazoles and quinoxalines
Atanu Bera,Motahar Sk,Khushboo Singh,Debasis Banerjee Chem. Commun. 2019 55 5958

4-甲基邻苯二胺(102-51-2)参考资料

Reaxys RN：

PubChem CID：

153404

4-甲基邻苯二胺(102-51-2) MSDS

基础信息

Name:	4-Methoxy-o-phenylenediamine Material Safety Data Sheet
Synonym:
CAS:	102-51-2

Section 1 - Chemical Product ? MSDS Name:4-Methoxy-o-phenylenediamine Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
102-51-2	4-Methoxy-o-phenylenediamine		unlisted

Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
? Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a tightly closed container. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 102-51-2: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 46 - 48 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H10N2O
Molecular Weight: 138.0828

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 102-51-2: ST2690000 LD50/LC50:
Not available.
Carcinogenicity:
4-Methoxy-o-phenylenediamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
? Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 102-51-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 102-51-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 102-51-2 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A