1121-47-7 (Β-呋喃酰一肟,Furan-2-aldoxime)

CAS号:
1121-47-7
中文名称:
Β-呋喃酰一肟
英文名称:
Furan-2-aldoxime
分子式:
C5H5NO2
分子量:
111.098701238632

Β-呋喃酰一肟(1121-47-7)名称与标识符

名称

中文别名:
2-糠醛肟;N-羟基琥珀酰亚胺磺酸钠盐;呋喃甲醛肟;糠醛肟;Β-呋喃酰一肟;
英文别名:
2-Furancarboxaldehyde,oxime;(E)-Furan-2-carbaldehyde oxime;2-Furaldehyde oxime;2-FURALDOXIME;Furfuraloxime;2-Furancarbaldehyde oxime;furfuraldehyde oxime;N-Hydroxy-2-furanylmethanimine;2-furancarboxaldehyde, oxime;furfural oxime;2-Furancarboxaldehyde oxime;1121-47-7;2-Furaldehyde, oxime, (E)-;J-002714;HMS1783M02;alpha-Furfuraldoxime;syn-Furfuraldoxime;Furan-2 carboxaldehyde oxime;PS-4057;NSC-49237;UYTMLDBQFLIQJA-XQRVVYSFSA-N;AI3-00484;CHEMBL3577784;EER4AX9NE4;alpha-Furfural oxime;2-FURALDEHYDE, OXIME;NSC1919;(NE)-N-(furan-2-ylmethylidene)hydroxylamine;2-furanaldoxime;2-Furfuraldoxime;Furan-2-aldoxime;NSC-1919;AKOS000304645;MFCD00014114;.alpha.-Furfuraldoxime;(E)-N-[(furan-2-yl)methylidene]hydroxylamine;NSC 1919;2-Furancarboxaldehyde, oxime, [C(E)]-;WLN: T5OJ B1UNQ;BRN 0108675;(Z)-furfuraldoxime;2-Furancarboxaldehyde, oxime, (E)-;2-FURALDEHYDEOXIME;Furfuraldoxime;NSC 49237;furan-2-carbaldehyde oxime;Z49568327;CS-0321320;NSC49237;620-03-1;Furfuryl oxime;.beta.-Furfural oxime;(2E)-furan-2-carbaldehyde oxime;(E)-1-(furan-2-yl)-N-hydroxymethanimine;STK325338;

标识符

MDL:
MFCD00014114
InChIKey:
UYTMLDBQFLIQJA-GQCTYLIASA-N
Inchi:
1S/C5H5NO2/c7-6-4-5-2-1-3-8-5/h1-4,7H/b6-4+
SMILES:
O1C=CC=C1/C=N/O

Β-呋喃酰一肟(1121-47-7)物化性质

实验特性

  • LogP : 1.08770
  • PSA : 45.73000
  • 折射率 : 1.4260 (estimate)
  • 沸点 : 208.19°C (rough estimate)
  • 熔点 : 78 °C
  • 闪点 : 56.5°C
  • 密度 : 1.3113 (rough estimate)

计算特性

  • 精确分子量 : 111.03200
  • 氢键供体数量 : 1
  • 氢键受体数量 : 3
  • 可旋转化学键数量 : 1
  • 同位素质量 : 111.032
  • 重原子数量 : 8
  • 复杂度 : 92.4
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 1
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 0.7
  • 拓扑分子极性表面积 : 45.7A^2

Β-呋喃酰一肟(1121-47-7)安全信息

Β-呋喃酰一肟(1121-47-7)海关数据

海关编码:
2932190090
海关数据:

中国海关编码:

2932190090

概述:

2932190090 其他结构上有非稠合呋喃环化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:20.0%

申报要素:

品名, 成分含量, 用途

Summary:

2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Β-呋喃酰一肟(1121-47-7)生产方法和用途

用途:
合成呋喃类药物

Β-呋喃酰一肟(1121-47-7)推荐厂家 更多厂家(6)

Β-呋喃酰一肟(1121-47-7) MSDS

基础信息

Name:2-Furaldehyde oxime 97% Material Safety Data Sheet
Synonym:
CAS:1121-47-7
Section 1 - Chemical Product ? MSDS Name:2-Furaldehyde oxime 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
1121-47-72-Furaldehyde oxime97%unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
? Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1121-47-7: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 78 - 80 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C5H5NO2
Molecular Weight: 111.1

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 1121-47-7: LT7900000 LD50/LC50:
Not available.
Carcinogenicity:
2-Furaldehyde oxime - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 1121-47-7: No information available.
Canada
CAS# 1121-47-7 is listed on Canada's NDSL List.
CAS# 1121-47-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1121-47-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A