12012-50-9 (三氯(乙烯基)铂酸钾(II),potassium trichloro(ethylene)platinate(II))

快速询单

结构式：

三氯(乙烯基)铂酸钾(II)MOL文件

CAS号：

12012-50-9

中文名称：

三氯(乙烯基)铂酸钾(II)

英文名称：

potassium trichloro(ethylene)platinate(II)

分子式：

C₂H₄Cl₃KPt

分子量：

368.588461875916

三氯(乙烯基)铂酸钾(II)(12012-50-9)名称与标识符

名称

中文别名：

三氯(乙烯基)铂酸钾(II);2-噻吩基硼酸甲基亚氨基二乙酸酯;三氯(乙烯基)铂(II)酸钾一水化合物;三氯乙烯基铂(II)酸钾;

英文别名：

potassium trichloro(ethylene)platinate(II);Ammonium Hexachloro Iridate (III) Hydrate;POTASSIUM TRICHLORO(ETHYLENE)PLATINATE (II) MONOHYDRATE;Potassium Trichoro (ethylene) Platinate (II)Monohydrate;potassium,ethene,platinum(2+),trichloride;EINECS 234-577-7;Platinate(1-),trichloro(eta2-ethene)-,potassium;Platinate(1-),trichloro(ethylene)-,potassium;Platinate(1-),trichloroethylene-,dipotassium;Potassium ethylenetrichloroplatinate(II);potassium trichloro(ethene)platinate(II);Potassium trichloroethyleneplatinate;Pt-93;Zeise-salt;NSC 162964;12012-50-9;Platinate(1-), trichloro(ethylene)-, potassium;Platinate(1-), trichloro(eta2-ethene)-, potassium;potassium;ethene;platinum(2+);trichloride;Platinate(1-), trichloro(.eta.2-ethene)-, potassium;Platinate(1-), trichloroethylene-, dipotassium;DTXCID801471476;OCUWJUARCXXPTH-UHFFFAOYSA-K;Platinate(1-), trichloro(eta2-ethene)-, potassium (1:1);Platinate(1-), trichloro(.eta.2-ethene)-, potassium (1:1);

标识符

MDL：

MFCD00050859

InChIKey：

OCUWJUARCXXPTH-UHFFFAOYSA-K

Inchi：

1S/C2H4.3ClH.K.Pt/c1-2;;;;;/h1-2H2;3*1H;;/q;;;;+1;+2/p-3

SMILES：

[Pt+2].[K+].[Cl-].[Cl-].[Cl-].C=C

三氯(乙烯基)铂酸钾(II)(12012-50-9)物化性质

实验特性

LogP : 2.92330
PSA : 9.23000
沸点 : °Cat760mmHg
闪点 : °C
颜色与性状 : 无可用
稳定性 : hygroscopic
溶解性 : 无可用
密度 : 2.880

计算特性

精确分子量 : 462.80400
氢键供体数量 : 0
氢键受体数量 : 0
可旋转化学键数量 : 0
同位素质量 : 366.866339
重原子数量 : 7
复杂度 : 0
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 6
疏水参数计算参考值（XlogP） : 无
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 0

三氯(乙烯基)铂酸钾(II)(12012-50-9)安全信息

三氯(乙烯基)铂酸钾(II)(12012-50-9)推荐厂家更多厂家(3)

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三氯(乙烯基)铂酸钾(II)(12012-50-9)合成路线

合成路线：1 步

反应条件：

1.1 Solvents: Water-d2

参考文献：

Carbon-hydrogen activation in aqueous medium. The diverse roles of platinum(II) and metallic platinum in the catalytic and stoichiometric oxidative functionalization of organic substrates including alkanes

Sen, Ayusman; Lin, Minren; Kao, Lien Chung; Hutson, Alan C., Journal of the American Chemical Society, 1992, 114(16), 6385-92

三氯(乙烯基)铂酸钾(II)(12012-50-9)上下游

白金

三氯(乙烯基)铂酸钾(II)(12012-50-9) MSDS

基础信息

Name:	Potassium trichloro(ethylene)platinate(ii) monohydrate Material Safety Data Sheet
Synonym:	Zeise's sal
CAS:	12012-50-9

Section 1 - Chemical Product ? MSDS Name:Potassium trichloro(ethylene)platinate(ii) monohydrate Material Safety Data Sheet
Synonym:Zeise's sal

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
12012-50-9	Potassium trichloro(ethylene)platinate		234-577-7

Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
? Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 12012-50-9: United States OSHA: 0.002 mg/m3 TWA (as Pt) (listed under Platin soluble salts).
Belgium - TWA: (listed as platinum soluble salts): 0.002 mg/m3 VL (as Pt) Japan: (listed as platinum soluble salts): 0.001 mg/m3 OEL (as Pt Malaysia: (listed as platinum soluble salts): 0.002 mg/m3 TWA (as Netherlands: (listed as platinum soluble salts): 0.002 mg/m3 MAC Pt) Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: yellow-green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 220 deg C dec
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C2H4Cl3KPt.H2O
Molecular Weight: 386.60

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Not available.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 12012-50-9: TP1880000 LD50/LC50:
Not available.
Carcinogenicity:
Potassium trichloro(ethylene)platinate(II) monohydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 12012-50-9: No information available.
Canada
CAS# 12012-50-9 is listed on Canada's NDSL List.
CAS# 12012-50-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12012-50-9 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A