12028-48-7 (氧化铵钨水合物,Ammonium metatungstate hydrate)

CAS号:
12028-48-7
中文名称:
氧化铵钨水合物
英文名称:
Ammonium metatungstate hydrate
分子式:
H24N6O12W3
分子量:
851.743549346924

氧化铵钨水合物(12028-48-7)名称与标识符

名称

中文别名:
氧化铵钨水合物;6-三氟甲基吡啶-2-硼酸;偏钨酸铵;偏钨酸铵水合物;钨酸铵水合物;氧化钨铵;偏钨酸;钨酸铵水合;
英文别名:
Ammonium metatungstate hydrate;Ammonium Tungsten Oxide Hydrate;hexaazanium,hydroxy-[(oxido(dioxo)tungstenio)oxy-dioxotungstenio]oxy-dioxotungsten,hydroxy-[[(oxido(dioxo)tungstenio)oxy-dioxotungstenio]oxy-dioxotungstenio]oxy-dioxotungsten,tungsten,trihydroxide,hydrate;12028-48-7;AMMONIUM TUNGSTATE, META;AMMONIUM TUNGSTEN OXIDE;AMMONIUM METATUNGSTATE;Ammoniummetatungstatehydrate(99.9+%-W);TUNGSTATEHEXAAMMONIUM;ammonium metatungstate hexahydrate;hexaammonium wolframate;

标识符

MDL:
MFCD00150662
InChIKey:
NMSQBYPCXHPPCW-UHFFFAOYSA-T
Inchi:
1S/6H3N.12O.3W/h6*1H3;;;;;;;;;;;;;;;/q;;;;;;;;;;;;6*-1;;;/p+6
SMILES:
[W](=O)(=O)([O-])[O-].[W](=O)(=O)([O-])[O-].[W](=O)(=O)([O-])[O-].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+]

氧化铵钨水合物(12028-48-7)物化性质

实验特性

  • LogP : 0.83160
  • PSA : 240.78000
  • 水溶性 : Soluble in water. Insoluble in alcohol.
  • 沸点 : °Cat760mmHg
  • 熔点 : 100 °C (dec.)(lit.)
  • 蒸气压 : No data available
  • 闪点 : °C
  • 溶解度 : H2O: 0.1 g/mL, clear, colorless
  • 颜色与性状 : 偏钨酸铵为白色结晶粉末
  • 溶解性 : 易溶于水,不溶于醇
  • 密度 : g/cm3

计算特性

  • 精确分子量 : 851.99800
  • 氢键供体数量 : 43
  • 氢键受体数量 : 46
  • 可旋转化学键数量 : 0
  • 同位素质量 : 2963.476621
  • 重原子数量 : 58
  • 复杂度 : 2100
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 14
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 589

氧化铵钨水合物(12028-48-7)国际标准相关数据

EINECS:
234-733-4

氧化铵钨水合物(12028-48-7)推荐厂家 更多厂家(17)

氧化铵钨水合物(12028-48-7) MSDS

基础信息


Section 1. Chemical Product and Company Identification
    Ammonium metatungstate
    Common Name/
    Trade Name
    Ammonium metatungstate

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at    
    least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
    Skin Contact        Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.    
    Cold water may be used.
    Serious Skin Contact        Not available.    
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention.
    Serious Inhalation        Not available.    
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
    clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not applicable.    
    Flammable Limits        Not applicable.    
    Not available.
    Products of Combustion
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    of Various Substances        Risks of explosion of the product in presence of static discharge: Not available.    
    Fire Fighting Media        Not applicable.    
    and Instructions
    Special Remarks on        Not available.    
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by    
    spreading water on the contaminated surface and dispose of according to local and regional authority
    requirements.
    Large Spill
    Isolate spill area and provide ventilation. Vacuum up spill using a HEPA air filter or use a shovel to pick up the
    spilled material and place material in a closed container for proper disposal. Take care not to raise dust. Finish
    cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be
    careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with
    local authorities.
    Ammonium metatungstate

Section 7. Handling and Storage
    Precautions        Do not breathe dust. Keep away from incompatibles such as oxidizing agents, alkalis.    
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area.    

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.    
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
    a Large Spill        to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist    
    BEFORE handling this product.
    TWA: 5 (mg/m3) from OSHA (PEL) [United States]
    Exposure Limits
    TWA: 1 (mg/m3) from ACGIH (TLV) [United States]
    Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid. (Crystalline powder. Powdered solid.)        Odor        Odorless.    
    Taste        Not available.    
    Molecular Weight        2938.41 g/mole    
    Color        White.    
    pH (1% soln/water)        Not available.    
    Not available.
    Boiling Point
    Melting Point        Not available.    
    Not available.
    Critical Temperature
    Specific Gravity        4 (Water = 1)    
    Vapor Pressure        Not applicable.    
    Vapor Density        Not available.    
    Volatility        Not available.    
    Not available.
    Odor Threshold
    Water/Oil Dist. Coeff.        Not available.    
    Ionicity (in Water)        Not available.    
    Dispersion Properties        See solubility in water.    
    Solubility        Partially soluble in cold water.    
    Insoluble in methanol, n-octanol.

Section 10. Stability and Reactivity Data
    Stability        The product is stable.    
    Not available.
    Instability Temperature
    Conditions of Instability        Incompatible materials, dust generation    
    Incompatibility with various        Reactive with oxidizing agents, alkalis.    
    substances
    Corrosivity        Non-corrosive in presence of glass.    
    Ammonium metatungstate
    Special Remarks on        Also incompatible with halogens.    
    Reactivity        Strong bases may release ammonia gas    
    Special Remarks on        Not available.    
    Corrosivity
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Inhalation. Ingestion.    
    Toxicity to Animals        LD50: Not available.    
    LC50: Not available.
    Chronic Effects on Humans May cause damage to the following organs: kidneys.
    Other Toxic Effects on        Hazardous in case of ingestion.    
    Humans        Slightly hazardous in case of skin contact (irritant), of inhalation.    
    Special Remarks on
    Not available.
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Acute Potential Health Effects:    
    Toxic Effects on Humans        Skin: May cause mild irritation of the skin with redness, and itching.    
    Eyes: May cause mild irritation of the eyes with redness, itching, watering.
    Inhalation: May cause irritation to th enose, mucous membranes and respiratory tract with sneezing, dry throat,
    and coughing.
    Ingestion: Tungstate compounds may cause changes in body weight and behavior.
    Chronic Potential Health Effects:
    Skin: Prolonged or repeated contact may cause dermatitis.
    Ingestion: Prolonged or repeated ingestion of large doses may cause kidney damage

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    BOD5 and COD        Not available.    
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation products may    
    arise.
    Toxicity of the Products        The products of degradation are as toxic as the original product.    
    of Biodegradation
    Not available.
    Special Remarks on the
    Products of Biodegradation

Section 13. Disposal Considerations
    Waste Disposal        Waste must be disposed of in accordance with federal, state and local environmental    
    control regulations.
    Ammonium metatungstate

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    Identification        Not applicable.    
    Not applicable.
    Special Provisions for
    Transport
    DOT (Pictograms)

Section 15. Other Regulatory Information and Pictograms
    TSCA 8(b) inventory: Ammonium metatungstate
    Federal and State
    Regulations
    California        California prop. 65: This product contains the following ingredients for which the State of California has found    
    to cause cancer which would require a warning under the statute: No products were found.
    Proposition 65
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found
    to cause birth defects which would require a warning under the statute: No products were found.
    Other Regulations        OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).    
    EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
    WHMIS (Canada) Not controlled under WHMIS (Canada).
    Other Classifications
    DSCL (EEC)        This product is not classified according Not applicable.    
    to the EU regulations.
    Health Hazard
    HMIS (U.S.A.)        2 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    2 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Ammonium metatungstate
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent.


SECTION 16 - ADDITIONAL INFORMATION
N/A