121009-93-6 (rac-二甲基硅基双(1-茚基)二氯化锆,rac-Dimethylsilylbis(1-indenyl)zirconium dichloride)

CAS号:
121009-93-6
中文名称:
rac-二甲基硅基双(1-茚基)二氯化锆
英文名称:
rac-Dimethylsilylbis(1-indenyl)zirconium dichloride
分子式:
C20H18Cl2SiZr
分子量:
448.572423458099

rac-二甲基硅基双(1-茚基)二氯化锆(121009-93-6)名称与标识符

名称

中文别名:
rac-二甲基硅基双(1-茚基)二氯化锆;{1-[4-(甲基磺酰基)苯基]丙基}胺;RAC-二甲基硅基二(1-茚基)二氯化锆;二甲基硅桥二茚基二氯化锆;二氯[REL-(1R,1'R)-(二甲基亚甲硅基)双[(1,2,3,3A,7A-Η)-1H-茚-1-亚基]]锆;RAC-二甲基硅烷基双(1-茚基)锆二氯化物;二甲基硅桥二茚基二氯化锆(147059-57-2);
英文别名:
rac-Dimethylsilylbis(1-indenyl)zirconium dichloride;dichlorozirconium,di(inden-1-yl)-dimethylsilane;[(CH3)2Si(indenyl)2]ZrCl2;dimethylsilanediylbis(indenyl)zirconium dichloride;dimethylsilylbis(1-indenyl)zirconium dichloride;Eurocen(R) 5037;rac-dimethylbis(indenyl)zirconocene dichloride;RAC-DIMETHYLSILYLBIS(INDENYL)ZIRCONIUMDICHLORIDE;rac-dimethylsilylenebis(indenyl)zirconium dichloride;Silane,di-1H-inden-1-yldimethyl-, zirconium complex;Rac-(dimethylsilylenebis(h5-1-indenyl))dichlorozirconium;Rac-[dimethylsilylenebis(1-indenyl)]dichlorozirconium;Rac-dimethylsilylenebis(1-indenyl)zirconium dichloride;rac-Dichloro[dimethylsilylenebis(1-indenylidene)]zirconium;Dimethylsilylbisindenylzirconiumdichloride;Bis-(1-indenyl)-dimethylsilyl zirconium dichloride;RAC-DIMETHYLSILYLENEBIS(1-INDENYL)ZIRCONIUM(IV) DICHLORIDE;Rac-[dimethylsilylbis(indenyl)zirconium dichloride;rac-Dimethylsilylbis(indenyl)zirconium dichloride;rac-Dimethylsilylbis(1-indenyl)zirconium dichloride, 97+%;rac-Dimethylsilylbis(1-indenyl)zirconiumdichloride,min.97%;rac-Dimethylsilylbis(1-indenyl)zirconium dichloride, min. 97%;

标识符

MDL:
MFCD00672108
InChIKey:
UWDIAYXWSZBXJP-UHFFFAOYSA-L
Inchi:
1S/C20H18Si.2ClH.Zr/c1-21(2,19-13-11-15-7-3-5-9-17(15)19)20-14-12-16-8-4-6-10-18(16)20;;;/h3-14H,1-2H3;2*1H;/q;;;+2/p-2
SMILES:
[C]12[C]([CH][CH][C]1C=CC=C2)[Si](C)(C)[C]1[CH][CH][C]2C=CC=C[C]12.[Zr](Cl)Cl |^1:0,1,2,3,4,12,13,14,15,20|

rac-二甲基硅基双(1-茚基)二氯化锆(121009-93-6)物化性质

实验特性

  • LogP : 5.96260
  • PSA : 0.00000
  • 熔点 : 140 °C
  • 颜色与性状 : 未确定
  • 溶解性 : 未确定
  • 敏感性 : moisture sensitive

计算特性

  • 精确分子量 : 445.96000
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 2
  • 重原子数量 : 24

rac-二甲基硅基双(1-茚基)二氯化锆(121009-93-6)安全信息

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rac-二甲基硅基双(1-茚基)二氯化锆(121009-93-6) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       rac-Dimethylsilylbis(1-indenyl)zirconium dichloride, min. 97%    
   CAS Registry Number:       121009-93-6    
   Formula:       (CH3)2Si(C9H6)2ZrCl2    
   EINECS Number:       none    
   Chemical Family:       organometallic complexes    
   Synonym:       None    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       121009-93-6       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to eyes and skin. May be harmful if swallowed or inhaled.    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes mild irritation of the eyes.    
   Skin Contact:       Causes slight irritation of the skin.    
   Inhalation:       Inhalation of dust may lead to irritation of the respiratory tract.    
   Ingestion:       No information is available on the physiological effects of ingestion. May be harmful if swallowed.    
   Acute Health Affects:       Irritating to eyes and skin. May be harmful if swallowed or inhaled.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep away from heat and
   Handling and Storage:
   direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Proram to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       orange powder    
   Molecular Weight:       448.53    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       moisture sensitive    
   Hazardous Polymerization:       none    
   Conditions to Avoid:       prolonged exposure to moisture    
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       carbon dioxide, carbon monoxide, hydrogen chloride, organic fumes and zirconium oxide    

SECTION 11: Toxicological Information
   RTECS Data:       No information available from the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       not listed on the TSCA inventory    
   SARA (Title 313):       not reportable under SARA Title (313)    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A