121359-48-6 (2-三丁基甲锡烷基噻唑,2-(Tributylstannyl)thiazole)

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Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
    Product name        : 2-Tributylstannylthiazole    

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Section 2. HAZARDS IDENTIFICATION
  Classification of the substance or mixture
    According to Regulation (EC) No1272/2008
    Acute toxicity, Dermal (Category 4)
    Acute toxicity, Oral (Category 3)
    Skin irritation (Category 2)
    Eye irritation (Category 2)
    Specific target organ toxicity - repeated exposure (Category 1)
    Acute aquatic toxicity (Category 1)
    According to European Directive 67/548/EEC as amended.
    Toxic if swallowed. Toxic: danger of serious damage to health by prolonged exposure through inhalation and if
    swallowed. Harmful in contact with skin. Irritating to eyes and skin. Very toxic to aquatic organisms, may cause
    long-term adverse effects in the aquatic environment.
  Label elements
    Pictogram
    Signal word        Danger    
    Hazard statement(s)
    H301        Toxic if swallowed.    
    H312        Harmful in contact with skin.    
    H315        Causes skin irritation.    
    H319        Causes serious eye irritation.    
    H372        Causes damage to organs through prolonged or repeated exposure.    
    H400        Very toxic to aquatic life.    
    Precautionary statement(s)
    P273        Avoid release to the environment.    
    P280        Wear protective gloves/protective clothing.    
    P301 + P310        IF SWALLOWED: Immediately call a POISON CENTER or    
    doctor/physician.
    P305 + P351 + P338        IF IN EYES: Rinse cautiously with water for several minutes. Remove    
    contact lenses, if present and easy to do. Continue rinsing.
    P314        Get medical advice/attention if you feel unwell.    
    Hazard symbol(s)
    T        Toxic    
    N        Dangerous for the environment    
    R-phrase(s)
    R21        Harmful in contact with skin.    
    R25        Toxic if swallowed.    
    R36/38        Irritating to eyes and skin.    
    R48/23/25        Toxic: danger of serious damage to health by prolonged exposure through    
    inhalation and if swallowed.
    R50/53        Very toxic to aquatic organisms, may cause long-term adverse effects in    
    the aquatic environment.
    S-phrase(s)
    S35        This material and its container must be disposed of in a safe way.    
    S36/37/39        Wear suitable protective clothing, gloves and eye/face protection.    
    S45        In case of accident or if you feel unwell, seek medical advice immediately    
    (show the label where possible).
    S60        This material and its container must be disposed of as hazardous waste.    
    S61        Avoid release to the environment. Refer to special instructions/ Safety data    
    sheets.
  Other hazards - none

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
    Formula        : C15H29NSSn    
    Molecular Weight        : 374,17 g/mol    
    CAS-No.        EC-No.        Index-No.        Classification        Concentration    
  2-Tributylstannylthiazole
    121359-48-6        -        050-008-00-3        Acute Tox. 4; Acute Tox. 3;        -    
    Skin Irrit. 2; Eye Irrit. 2; STOT
    RE 1; Aquatic Acute 1; H301,
    H312, H315, H319, H372,
    H400
    T, N, R21 - R25 - R36/38 -
    R48/23/25 - R50/53
    For the full text of the H-Statements mentioned in this Section, see Section 16.

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Section 4. FIRST AID MEASURES
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.
  In case of skin contact
    Wash off with soap and plenty of water. Consult a physician.
  In case of eye contact
    Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
  If swallowed
    Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

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Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
  Special protective equipment for fire-fighters
    Wear self contained breathing apparatus for fire fighting if necessary.

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Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions
    Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
    Evacuate personnel to safe areas.
  Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
    environment must be avoided.
  Methods and materials for containment and cleaning up
    Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
    containers for disposal.

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Section 7. HANDLING AND STORAGE
  Precautions for safe handling
    Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
    Normal measures for preventive fire protection.
  Conditions for safe storage
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
    opened must be carefully resealed and kept upright to prevent leakage.

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
  Personal protective equipment
  Respiratory protection
    Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with
    multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to
    engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
    respirator. Use respirators and components tested and approved under appropriate government
    standards such as NIOSH (US) or CEN (EU).
  Hand protection
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
    standard EN 374 derived from it.
    Handle with gloves.
  Eye protection
    Face shield and safety glasses
  Skin and body protection
    Choose body protection according to the amount and concentration of the dangerous substance at the
    work place.
  Hygiene measures
    Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the
    product.

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Appearance
    Form        liquid    
    Colour        colourless    
  Safety data
    pH        no data available    
    Melting point        no data available    
    Boiling point        307 - 309 °C - lit.    
    Flash point        > 110 °C - closed cup    
    Ignition temperature        no data available    
    Lower explosion limit        no data available    
    Upper explosion limit        no data available    
    Density        1,19 g/cm3 at 25 °C    
    Water solubility        no data available    

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Section 10. STABILITY AND REACTIVITY
  Chemical stability
    Stable under recommended storage conditions.
  Conditions to avoid
    no data available
  Materials to avoid
    Strong oxidizing agentsStrong oxidizing agents, Strong mineral acids, Bases
  Hazardous decomposition products
    Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx),
    Sulphur oxides, Tin/tin oxides

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Section 11. TOXICOLOGICAL INFORMATION
  Acute toxicity
    no data available
  Skin corrosion/irritation
    no data available
  Serious eye damage/eye irritation
    no data available
  Respiratory or skin sensitization
    no data available
  Germ cell mutagenicity
    no data available
  Carcinogenicity
    IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
    probable, possible or confirmed human carcinogen by IARC.
  Reproductive toxicity
    no data available
  Specific target organ toxicity - single exposure
    no data available
  Specific target organ toxicity - repeated exposure
    Causes damage to organs through prolonged or repeated exposure.
  Aspiration hazard
    no data available
  Potential health effects
  Inhalation        Toxic if inhaled. May cause respiratory tract irritation.    
  Ingestion        Toxic if swallowed.    
  Skin
    Harmful if absorbed through skin. Causes skin irritation.
  Eyes        Causes eye irritation.    
  Signs and Symptoms of Exposure
    To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
    investigated.
  Additional Information
    RTECS: no data available

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Section 12. ECOLOGICAL INFORMATION
  Toxicity
    no data available
  Persistence and degradability
    no data available
  Bioaccumulative potential
    no data available
  Mobility in soil
    no data available
  PBT and vPvB assessment
    no data available
  Other adverse effects
    Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

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Section 13. DISPOSAL CONSIDERATIONS
  Product
    Observe all federal, state, and local environmental regulations. Contact a licensed professional waste
    disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn
    in a chemical incinerator equipped with an afterburner and scrubber.
  Contaminated packaging
    Dispose of as unused product.

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Section 14. TRANSPORT INFORMATION
  ADR/RID
    UN-Number: 2788 Class: 6.1        Packing group: II    
    Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (2-Tributylstannylthiazole)
  IMDG
    UN-Number: 2788 Class: 6.1        Packing group: II        EMS-No: F-A, S-A    
    Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (2-Tributylstannylthiazole)
    Marine pollutant: Marine pollutant
  IATA
    UN-Number: 2788 Class: 6.1        Packing group: II    
    Proper shipping name: Organotin compound, liquid, n.o.s. (2-Tributylstannylthiazole)

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Section 15. REGULATORY INFORMATION
    This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

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Section 16. OTHER INFORMATION
  Text of H-code(s) and R-phrase(s) mentioned in Section 3
    Acute Tox.        Acute toxicity    
    Aquatic Acute        Acute aquatic toxicity    
    Eye Irrit.        Eye irritation    
    H301        Toxic if swallowed.    
    H312        Harmful in contact with skin.    
    H315        Causes skin irritation.    
    H319        Causes serious eye irritation.    
    H372        Causes damage to organs through prolonged or repeated exposure.    
    H400        Very toxic to aquatic life.    
    Skin Irrit.        Skin irritation    
    STOT RE        Specific target organ toxicity - repeated exposure    
    N        Dangerous for the environment    
    T        Toxic    
    R21        Harmful in contact with skin.    
    R25        Toxic if swallowed.    
    R36/38        Irritating to eyes and skin.    
    R48/23/25        Toxic: danger of serious damage to health by prolonged exposure through inhalation    
    and if swallowed.
    R50/53        Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic    
    environment.
  Further information
    Copyright 2010 Co. License granted to make unlimited paper copies for internal use only.
    The above information is believed to be correct but does not purport to be all inclusive and shall be used
    only as a guide. The information in this document is based on the present state of our knowledge and is
    applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee
    of the properties of the product. Co., shall not be held liable for any damage resulting from
    handling or from contact with the above product. See reverse side of invoice or packing slip for additional
    terms and conditions of sale.