12182-82-0 (氧化铬,oxo(oxochromiooxy)chromium;hydrate)

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Section 1: Product Identification
   Chemical Name:       Chromium (III) oxide hydrate,98%    
   CAS Registry Number:       12182-82-0    
   Formula:       Cr2O3.XH2O    
   EINECS Number:       none    
   Chemical Family:       metal oxide    
   Synonym:       chromic oxide, chrome green.    

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Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       12182-82-0       100%       0.5mg/m3 (as Cr)       0.5mg/m3 (as Cr)    

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Section 3: Hazards Identification
   Irritating to skin, eyes and respiratory tract. May cause sensitization by skin contact. Possible risk of
   Emergency Overview:
   irreversible effects.
   Primary Routes of Exposure:       Ingestion, Inhalation of dust.    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin. May cause sensitization by skin contact.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No specific information is available on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract. May cause sensitization by skin contact.    
   Chronic Health Affects:       Possible risk of irreversible effects.    
   NTP:       yes    
   IARC:       No    
   OSHA:       No    

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SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       material is non-flammable    
   Special Fire Fighting Procedures:       No special fire-fighting procedures. The material is non-flammable.    
   Hazardous Combustion and       Less than 0.1% toxic hexavalent chromium could be formed at high temperature.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

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SECTION 7: Handling and Storage
   Handling and Storage:       No special storage conditions.    

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SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

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SECTION 9: Physical and Chemical Properties
   Color and Form:       green pwdr.    
   Molecular Weight:       151.99    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

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SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable solid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       active metals, hydrogen fluoride, oxygen difluoride, and other very strong oxidizers.    
   Decomposition Products:       Less than 0.1% toxic hexavalent chromium    

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SECTION 11: Toxicological Information
   Inhalation (Rat) TCLo: 150mg/m3/4H/6W-I; Intraperitoneal (rat) TDLo (tumor) 90mg/kg; Intrapleural (rat) TDLo
   RTECS Data:
   (tumor) 45 mg/kg; Intratracheal (rat) TDLo (tumor) 90 mg/Kg
   Carcinogenic Effects:       Insufficient data    
   Mutagenic Effects:       Possible mutagen    
   Tetratogenic Effects:       No data available    

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SECTION 12: Ecological Information
   Ecological Information:       No information available    

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SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

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SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

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SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound: See Category Code N090 for reporting.    
   Second Ingredient:       none    

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SECTION 16 - ADDITIONAL INFORMATION
N/A