12266-72-7 ((1,5-环辛二烯)二碘铂(II),Diiodo(1,5-cyclooctadiene)platinum(II))

CAS号:
12266-72-7
中文名称:
(1,5-环辛二烯)二碘铂(II)
英文名称:
Diiodo(1,5-cyclooctadiene)platinum(II)
分子式:
C8H12I2Pt
分子量:
557.067830085754

(1,5-环辛二烯)二碘铂(II)(12266-72-7)名称与标识符

名称

中文别名:
(1,5-环辛二烯)二碘铂(II);硫化钼(Ⅲ);(1,5-环辛二烯)二碘化铂;
英文别名:
Diiodo(1,5-cyclooctadiene)platinum (II);(1,5-Cyclooctadiene)diiodoplatinum(II);(1Z,5Z)-cycloocta-1,5-diene,platinum(2+),diiodide;Cyclooctadiene Diiodo Platinum (II);(Cyclooctadiene)diiodoplatinum;Diiodo(cyclooctadiene)platinum;MFCD00050491;doi:10.14272/SGSFNZOKVYTGRR-PHFPKPIQSA-L.1;AKOS024259164;SGSFNZOKVYTGRR-PHFPKPIQSA-L;12266-72-7;SCHEMBL1449928;SCHEMBL9415156;CS-0086015;10.14272/SGSFNZOKVYTGRR-PHFPKPIQSA-L.1;((1,2,5,6-eta)-Cycloocta-1,5-diene)diiodoplatinum;Diiodo(1,5-cyclooctadiene)platinum(II);(1Z,5Z)-cycloocta-1,5-diene;diiodoplatinum;

标识符

MDL:
MFCD00050491
InChIKey:
SGSFNZOKVYTGRR-PHFPKPIQSA-L
Inchi:
1S/C8H12.2HI.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
SMILES:
[Pt](I)I.C1C=CCCC=CC1 |c:3,7|

(1,5-环辛二烯)二碘铂(II)(12266-72-7)物化性质

实验特性

  • LogP : 4.44170
  • PSA : 0.00000
  • 水溶性 : Insoluble in water.
  • 沸点 : No data available
  • 熔点 : 260°C (dec.)
  • 蒸气压 : No data available
  • 闪点 : No data available
  • 颜色与性状 : 灰色粉末
  • 溶解性 : 未确定
  • 密度 : g/cm3

计算特性

  • 精确分子量 : 556.86800
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 0
  • 同位素质量 : 556.86761
  • 重原子数量 : 11
  • 复杂度 : 72.6
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 2
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 4
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0

(1,5-环辛二烯)二碘铂(II)(12266-72-7)国际标准相关数据

EINECS:
235-538-7

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(1,5-环辛二烯)二碘铂(II)(12266-72-7)参考资料

Reaxys RN:
PubChem CID:

(1,5-环辛二烯)二碘铂(II)(12266-72-7) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Diiodo(1,5-cyclooctadiene)platinum (II), 99%    
   CAS Registry Number:       12266-72-7    
   Formula:       PtI2(1,5-C8H12)    
   EINECS Number:       235-538-7    
   Chemical Family:       organometallic complexes    
   Synonym:       1,5-cyclooctadieneplatinum diiodide    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       12266-72-7       100%       1mg/m3(as-Pt)       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin    
   Eye Contact:       Causes mild to moderate irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.    
   Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds may lead to wheezing, coughing,
   Acute Health Affects:
   and running of the nose. Skin exposure may lead to dermatitis.
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic and corrosive fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry place in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       To minimize exposure, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       To minimize exposure, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow pwdr.    
   Molecular Weight:       557.08    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents, halogens, and active metals    
   Decomposition Products:       carbon dioxide, carbon monoxide, iodine, organic fumes and platinum salts.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Not regulated by Title 313.    
   Second Ingredient:       None    


SECTION 16 - ADDITIONAL INFORMATION
N/A