13440-24-9 (内消旋-1,2-二溴-1,2-联苯乙烷,meso-1,2-Dibromo-1,2-diphenylethane)

CAS号:
13440-24-9
中文名称:
内消旋-1,2-二溴-1,2-联苯乙烷
英文名称:
meso-1,2-Dibromo-1,2-diphenylethane
安全信息:
分子式:
C14H12Br2
分子量:
340.053082466125

内消旋-1,2-二溴-1,2-联苯乙烷(13440-24-9)名称与标识符

名称

中文别名:
内消旋-1,2-二溴-1,2-联苯乙烷;内消旋-1,2-二溴-1,2-二苯基乙烷;1,2-二溴-1,2-二苯基乙烷;meso-1,2-Dibromo-1,2-diphenylethane 内消旋-1,2-二溴-1,2-二苯基乙烷;N,N,N',N'-四丙基丙二酰胺;内消旋-1,2-二苯基-1,2-二溴乙烷;二溴化芪;内消旋-1,2-二溴-1,2-联苯乙烷,97%;
英文别名:
meso-1,2-dibromo-1,2-diphenylethane;Dibromodiphenylethane;1,2-DIBROMO-1,2-DIPHENYLETHANE;(1,2-dibromo-2-phenylethyl)benzene;meso-Stilbene Dibromide;STILBENE DIBROMIDE;TIMTEC-BB SBB008899;A,A'-DIBROMOBIBENZYL;meso-Dibromostilbene;(1R,2S)-1,2-Dibromo-1,2-diphenylethane;LABOTEST-BB LT00159599;[(1S)-1,2-Dibromo-2-phenylethyl]benzene;J-006532;SCHEMBL13590015;D0183;meso-1,2-Dibromo-1,2-diphenylethane, >=97%;CHEMBL3115205;AKOS004908272;CS-0337721;DTXSID601292410;D89610;13440-24-9;MFCD00085299;Q63848697;GKESIQQTGWVOLH-OKILXGFUSA-N;[(1R,2S)-1,2-dibromo-2-phenylethyl]benzene;

标识符

MDL:
MFCD00085299
InChIKey:
GKESIQQTGWVOLH-OKILXGFUSA-N
Inchi:
1S/C14H12Br2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14H/t13-,14+
SMILES:
Br[C@H](C1C=CC=CC=1)[C@H](C1C=CC=CC=1)Br
BRN:
2050820

内消旋-1,2-二溴-1,2-联苯乙烷(13440-24-9)物化性质

实验特性

  • LogP : 5.25880
  • PSA : 0.00000
  • 折射率 : 1.637
  • 水溶性 : Insoluble in water.
  • 沸点 : 323.8 °C at 760 mmHg
  • 熔点 : 241 °C (dec.)(lit.)
  • 闪点 : 173.2 °C
  • 颜色与性状 : 白色粉末
  • 溶解性 : 不能溶解的
  • 密度 : 1.613

计算特性

  • 精确分子量 : 337.93100
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 3
  • 同位素质量 : 337.931
  • 重原子数量 : 16
  • 复杂度 : 171
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 2
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 4.8
  • 拓扑分子极性表面积 : 0

内消旋-1,2-二溴-1,2-联苯乙烷(13440-24-9)海关数据

海关编码:
2903999090
海关数据:

中国海关编码:

2903999090

概述:

2903999090 其他芳烃卤化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

内消旋-1,2-二溴-1,2-联苯乙烷(13440-24-9)推荐厂家 更多厂家(14)

内消旋-1,2-二溴-1,2-联苯乙烷(13440-24-9)参考资料

Reaxys RN:
2050821
Beilstein:
5,602
PubChem CID:

内消旋-1,2-二溴-1,2-联苯乙烷(13440-24-9) MSDS

基础信息

  meso-1,2-Dibromo-1,2-diphenylethane      Revision number: 5    
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        meso-1,2-Dibromo-1,2-diphenylethane    
    
  Revision number:        5    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified    
  HEALTH HAZARDS
  Acute toxicity (Oral)        Category 4    
    Category 2
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 2A    
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Warning    
  Hazard statements        Harmful if swallowed    
    Causes skin irritation
    Causes serious eye irritation
  Precautionary statements:
    Do not eat, drink or smoke when using this product.
  [Prevention]
    Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
  [Response]        IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.    
    Rinse mouth.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.
  [Disposal]        Dispose of contents/container through a waste management company authorized by    
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
  Components:        meso-1,2-Dibromo-1,2-diphenylethane    
    >97.0%(T)
  Percent:
  CAS Number:        13440-24-9    
  meso-1,2-Dibromo-1,2-diphenylethane

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Synonyms:        meso-Stilbene Dibromide    
  Chemical Formula:        C14H12Br2    

Section 4. FIRST AID MEASURES
    Remove victim to fresh air and keep at rest in a position comfortable for breathing.
  Inhalation:
    Get medical advice/attention if you feel unwell.
    Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
  Skin contact:
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
    Rinse cautiously with water for several minutes. Remove contact lenses, if present
  Eye contact:
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.    
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-    
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
    generate poisonous fume.
  from the chemical:
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
    Handling is performed in a well ventilated place. Wear suitable protective equipment.
  Technical measures:
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.    
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
    Install a closed system or local exhaust as possible so that workers should not be
  Engineering controls:
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.    
  Eye protection:        Safety glasses. A face-shield, if the situation requires.    
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.
  meso-1,2-Dibromo-1,2-diphenylethane

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid    
    Crystal- Powder
  Form:
  Colour:        White - Slightly pale yellow    
    No data available
  Odour:
  pH: No data available
  Melting point/freezing point:No data available
  Boiling point/range:        No data available    
    No data available
  Flash point:
  Flammability or explosive
  limits:
  Lower:        No data available    
    No data available
  Upper:
  Relative density:        No data available    
  Solubility(ies):
  [Water]        No data available    
    No data available
  [Other solvents]

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.    
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen bromide
  products:

Section 11. TOXICOLOGICAL INFORMATION
    No data available
  Acute Toxicity:
  Skin corrosion/irritation: No data available
    No data available
  Serious eye
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
    No data available
  IARC =
  NTP =        No data available    
    No data available
  Reproductive toxicity:

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available    
  Crustacea:        No data available    
  Algae:        No data available    
  Persistence / degradability: No data available
  Bioaccumulative        No data available    
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available    
  Soil adsorption (Koc):        No data available    
  Henry's Law        No data available    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.
  meso-1,2-Dibromo-1,2-diphenylethane

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations    
  UN-No:        Not listed    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A