13453-07-1 (氯化金,Gold(III) Chloride)

结构式:
CAS号:
13453-07-1
中文名称:
氯化金
英文名称:
Gold(III) Chloride
安全信息:
分子式:
AuCl3
分子量:
303.325550079346
简介:
氯化金,是最常见的无机金化合物,化学式是AuCl3。名称中的罗马数字表明金的化合价为+3,这是它众多化合物中最为稳定的价态。金亦会形成另一种氯化物——氯化亚金(AuCl),它没有AuCl3稳定。另外,把金溶于王水中便会产生氯金酸(H[AuCl4]),有时也会称为“三氯化金”或“三水合氯化金(III)”。
氯化金(III)吸湿性很强,极易溶于水及乙醇。温度高于160 °C或光照时会分解,并产生多种有大量配体的配合物。

氯化金(13453-07-1)名称与标识符

名称

中文别名:
氯化金;三氯化金;氯化金(III);氯化金(III)水合物;氯化金,AR;氯化金,Gold trichloride;氯金酸;无水氯化金;氯金水合物;三氯化金水溶液;四氯金酸;水合氯金酸;三氯化金 1G;氯化金(+4℃);氯化金/ 水合氯金酸;氯化金(+4℃)(阴凉);
英文别名:
Gold(III) chloride;Goldchloride Solution;Gold trichloride;Gold(III) chloride hydrate;Gold(III) chloride solution;Hydrogen tetrachloroaurate(III) hydrate;Tetrachloroauric(III) acid;Trichlorogold;Auric chloride;Auric trichloride;Gold chloride;CHLORAUIC ACID;goldchloride(aucl3);digold hexachloride;GOLD CHLORIDE, BROWN;auricchloride;aurictrichloride;Gold chloride (AuCl3);Gold(III)chloride;Goldchlorid;AuCl3;gold(III)-chloride;gold(3+) chloride;Gold (III) chloride;[AuCl3];DSSTox_CID_24379;DSSTox_RID_80183;DSSTox_GSID_44379;Gold(III) chloride, 99%;KSC491S9R;RJHLTVSLYWWTEF-UHFFFAOYSA-K;Tox21_302116;Gold(III) chloride (64.4% Au);BDBM50153290;NCGC0;chlorauride;Q174129;CHEMBL182062;UNII-15443PR153;CS-0077823;DTXCID2024379;13453-07-1;sodium tetrachloridoauratesodium tetrachloridoaurate(1-)sodium tetrachloridoaurate(III);Gold(III) chloride, SAJ special grade (dihydrate), >=98.5%;DTXSID4044379;Gold(III) chloride, 99% (99.9%-Au);EINECS 236-623-1;FT-0626802;CAS-13453-07-1;15443PR153;CHEBI:30076;Slow Digestion Diarrhea;Gold(III) chloride, >=99.99% trace metals basis;AKOS024437575;NCGC00255972-01;(AuCl3);Gold(III) chloride; Gold trichloride;

标识符

MDL:
MFCD00014172
InChIKey:
RJHLTVSLYWWTEF-UHFFFAOYSA-K
Inchi:
1S/Au.3ClH/h;3*1H/q+3;;;/p-3
SMILES:
[Au](Cl)(Cl)Cl

氯化金(13453-07-1)物化性质

实验特性

  • LogP : -8.99050
  • PSA : 0.00000
  • Merck : 14,4521
  • 水溶性 : 溶解
  • 沸点 : °Cat760mmHg
  • 熔点 : 254 ºC
  • 闪点 : °C
  • 颜色与性状 : 红宝石色结晶(经升华而得)或红褐色至暗红色的结晶块。
  • 溶解性 : 易溶于水
  • 敏感性 : Hygroscopic
  • 密度 : 3.9 g/mL at 25 °C

计算特性

  • 精确分子量 : 301.87300
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 0
  • 同位素质量 : 301.87311
  • 重原子数量 : 4
  • 复杂度 : 8
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0

氯化金(13453-07-1)安全信息

氯化金(13453-07-1)国际标准相关数据

EINECS:
236-623-1

氯化金(13453-07-1)生产方法和用途

用途:
用于摄影术、镀金、特种墨水、药物、瓷金和红玻璃等。

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氯化金(13453-07-1)参考资料

Reaxys RN:
PubChem CID:

氯化金(13453-07-1) MSDS

基础信息

Name:Gold (III) Chloride 99% Material Safety Data Sheet
Synonym:Auric Chloride; Auric Trichloride; Gold Trichloride
CAS:13453-07-1
Section 1 - Chemical Product ? MSDS Name:Gold (III) Chloride 99% Material Safety Data Sheet
Synonym:Auric Chloride; Auric Trichloride; Gold Trichloride

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
13453-07-1Gold (III) Chloride99%236-623-1
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs moisture from the air).Light sensitive.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed. Adverse reproductive effects have been reported in animals.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Store protected from light. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 13453-07-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Powder
Color: brown - gold
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 254 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: AuCl3
Molecular Weight: 303.32

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, light, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, ammonia, amines.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, oxides of chlorine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 13453-07-1: MD5420000 LD50/LC50:
Not available.
Carcinogenicity:
Gold (III) Chloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13453-07-1: 2
Canada
CAS# 13453-07-1 is listed on Canada's DSL List.
CAS# 13453-07-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13453-07-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A