Section 1 - Chemical Product ? MSDS Name:Iron(II) chloride tetrahydrate 99+% Material Safety Data Sheet
Synonym:Ferrous chloride tetrahydrat
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS| CAS# | Chemical Name | content | EINECS# |
| 13478-10-9 | Iron (II) chloride | 99+% | unlisted |
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
Section 3 - HAZARDS IDENTIFICATION ? EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.Hygroscopic (absorbs moisture from the air).Air sensitive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
Exposure may cause irritation and possible burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. Acute exposure to excessive levels of ferrous compounds can cause liver and kidney damage. May cause CNS irritation.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic ingestion may cause effects similar to those of acute ingestion.
Section 4 - FIRST AID MEASURES ? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Antidote: The use of Deferoxamine as a chelating agent should be determined only by qualified medical personnel.
Section 5 - FIRE FIGHTING MEASURES ? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES ? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.
Section 7 - HANDLING and STORAGE ? Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ? Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 13478-10-9: Belgium - TWA: (listed as iron salts (soluble)): 1 mg/m3 VLE (as Malaysia: (listed as iron salts (soluble)): 1 mg/m3 TWA (as Fe) Netherlands: (listed as iron salts (soluble)): 1 mg/m3 MAC (as Fe Spain: (listed as iron salts (soluble)): 1 mg/m3 VLA-ED (as Fe) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES ?
Physical State: Solid
Color: light green
Odor: Not available.
pH: Not available.
Vapor Pressure: 10 mm Hg @ 693 deg
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 150 deg C
Solubility in water: 1600g/l (10C) in H2O
Specific Gravity/Density: Not available.
Molecular Formula: FeCl2.4H2O
Molecular Weight: 198.8066
Section 10 - STABILITY AND REACTIVITY ? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Ethylene oxide, potassium,sodium, strong oxidizing agents, ozonides, metal halides..
Hazardous Decomposition Products:
Hydrogen chloride, oxides of iron.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION ? RTECS#:
CAS# 13478-10-9: NO5600000 LD50/LC50:
Not available.
Carcinogenicity:
Iron (II) chloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION ? Ecotoxicity:
Water danger/protection: WGK1
Section 13 - DISPOSAL CONSIDERATIONS ? Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION ?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION ?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 13478-10-9: 1
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13478-10-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13478-10-9 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
SECTION 16 - ADDITIONAL INFORMATION N/A
GHS07 
3146474380 
