137049-02-6 (1,2-二甲基-1H-咪唑-4-磺酰氯,1,2-DIMETHYL-1H-IMIDAZOLE-4-SULFONYL CHLORIDE)

快速询单

结构式：

1,2-二甲基-1H-咪唑-4-磺酰氯MOL文件

CAS号：

137049-02-6

中文名称：

1,2-二甲基-1H-咪唑-4-磺酰氯

英文名称：

1,2-DIMETHYL-1H-IMIDAZOLE-4-SULFONYL CHLORIDE

分子式：

C₅H₇ClN₂O₂S

分子量：

194.639278650284

1,2-二甲基-1H-咪唑-4-磺酰氯(137049-02-6)名称与标识符

名称

中文别名：

1,2-二甲基-1H-咪唑-4-磺酰氯;1,2-二甲基咪唑-4-磺酰氯;

英文别名：

1,2-DIMETHYL-1H-IMIDAZOLE-4-SULFONYL CHLORIDE;1,2-dimethylimidazole-4-sulfonyl chloride;1,2-DIMETHYLIMIDAZOLE-4-SULPHONYL CHLORIDE;1H-Imidazole-4-sulfonylchloride, 1,2-dimethyl-;(1,2-dimethyl-1H-imidazol-4-yl)sulfonyl chloride;1,2-dimethyl-1H-imidazol-4-sulfonyl chloride;1,2-dimethyl-1h-imidazole-4-sulphonyl chloride;1,2-dimethyl-4-imidazolesulfonyl chloride;1H-Imidazole-4-sulfonylchloride,1,2-dimethyl;1,2-dimethyl 1h imidazole-4-sulfonyl chloride;EN300-58948;J-503830;SCHEMBL388492;AT12182;A807177;BP-10975;1H-Imidazole-4-sulfonyl chloride, 1,2-dimethyl-;JPAFTHVNSBWVQJ-UHFFFAOYSA-N;F2158-1664;1H-Imidazole-4-sulfonylchloride,1,2-dimethyl-;1,2-Dimethyl-1H-imidazole-4-sulfonylchloride;MFCD01313780;AS-19772;SY179880;AKOS002663610;DTXSID70371234;CS-0074848;1,2-dimethylimidazole-4-sulphonylchloride;FT-0606423;137049-02-6;ALBB-021363;STK801344;DTXCID90322268;DB-004792;

标识符

MDL：

MFCD01313780

InChIKey：

JPAFTHVNSBWVQJ-UHFFFAOYSA-N

Inchi：

1S/C5H7ClN2O2S/c1-4-7-5(3-8(4)2)11(6,9)10/h3H,1-2H3

SMILES：

ClS(C1=CN(C)C(C)=N1)(=O)=O

1,2-二甲基-1H-咪唑-4-磺酰氯(137049-02-6)物化性质

实验特性

LogP : 1.73680
PSA : 60.34000
折射率 : 1.605
沸点 : 357.5±15.0 °C at 760 mmHg
熔点 : 91 °C
蒸气压 : 0.0±0.8 mmHg at 25°C
闪点 : 170.0±20.4 °C
颜色与性状 : 未确定
溶解性 : 未确定
密度 : 1.5±0.1 g/cm3

计算特性

精确分子量 : 193.99200
氢键供体数量 : 0
氢键受体数量 : 4
可旋转化学键数量 : 1
同位素质量 : 193.992
重原子数量 : 11
复杂度 : 235
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 0.8
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 60.3A^2

1,2-二甲基-1H-咪唑-4-磺酰氯(137049-02-6)安全信息

安全术语： S26-36/37/39
安全说明： S26-S36/37/39
风险术语： R34
危险品标志： Xi C
危险品运输编号： 3261
危害声明：H303+H313+H333
警示性声明：P264+P280+P305+P351+P338+P337+P313
储存条件： storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)
危险类别码： 34
信号词： warning
HazardClass： MOISTURE SENSITIVE, CORROSIVE

1,2-二甲基-1H-咪唑-4-磺酰氯(137049-02-6)国际标准相关数据

EINECS：

1,2-二甲基-1H-咪唑-4-磺酰氯(137049-02-6)海关数据

海关编码：

2933290090

海关数据：

中国海关编码：

2933290090

概述：

2933290090. 其他结构含非稠合咪唑环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

申报要素：

品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

Summary：

2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1,2-二甲基-1H-咪唑-4-磺酰氯(137049-02-6)推荐厂家更多厂家(11)

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1,2-二甲基-1H-咪唑-4-磺酰氯(137049-02-6)参考资料

Reaxys RN：

PubChem CID：

2736256

1,2-二甲基-1H-咪唑-4-磺酰氯(137049-02-6) MSDS

基础信息

Name:	1 2-Dimethyl-1H-imidazole-4-sulfonyl chloride 95+% Material Safety Data Sheet
Synonym:
CAS:	137049-02-6

Section 1 - Chemical Product ? MSDS Name:1 2-Dimethyl-1H-imidazole-4-sulfonyl chloride 95+% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
137049-02-6	1,2-Dimethyl-1H-imidazole-4-sulfonyl c	95+%	unlisted

Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
? Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a tightly closed container. Store in a dry area. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 137049-02-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 91 - 94 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C5H7ClN2O2S
Molecular Weight: 195

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 137049-02-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,2-Dimethyl-1H-imidazole-4-sulfonyl chloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 137049-02-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 137049-02-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 137049-02-6 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A