14649-73-1 (六硝基钴(III)酸钠,Cobaltate(3-), hexakis(nitrito-O)-, trisodium, (OC-6-11)-)

快速询单

结构式：

六硝基钴(III)酸钠MOL文件

CAS号：

14649-73-1

中文名称：

六硝基钴(III)酸钠

英文名称：

Cobaltate(3-), hexakis(nitrito-O)-, trisodium, (OC-6-11)-

分子式：

CoN₆Na₃O₁₂

分子量：

403.935512542725

六硝基钴(III)酸钠(14649-73-1)名称与标识符

名称

中文别名：

六硝基钴(III)酸钠;Boc-L-烯丙基甘氨酸二环己胺盐;六硝基钴(III)酸钠, ACS;六硝酸钴钠;六硝酸钴钠,钾试剂;(OC-6-11)-六亚硝酸合钴酸(3-)钠;亚硝酸钴钠;(OC-6-11)-六亚硝酸合钴酸钠;

英文别名：

Sodium hexanitritocobaltate (III);1-METHYL-5-(TRIFLUOROMETHYL)-1H-INDAZOL-3-AMINE;SODIUM HEXANITRITOCOBALTATE (III), (ACS);SODIUM COBALTINITRITE;trisodium,cobalt(3+),hexanitrite;SODIUM COBALTNITRITE;COBALT SODIUM NITRITE;COBALTIC SODIUM NITRITE;SODIUM HEXANITROCOBALTATE;COBALT(III) SODIUM NITRITE;SODIUM HEXANITROCOBALTATE(+3);SODIUM HEXANITROCOBALTATE(III);Sodium hexanitritocobaltate(3-);SODIUM HEXANITRITOCOBALTATE(III);trisodium cobalt(3+) hexanitrite;cobaltic trisodium hexanitrite;cobalt(3+) sodium nitrite(1:3:6);Cobaltate(3-), hexanitrito-, trisodium;na3[co(no2)6];Cobalt(3+) sodium nitrite (1/3/6);A809374;Cobaltate(3-), hexakis(nitrito-O)-, trisodium, (OC-6-11)-;trisodium;cobalt(3+);hexanitrite;15079-20-6;DTXSID90932846;14649-73-1;

标识符

MDL：

MFCD00003512

InChIKey：

ZEBNDJQGEZXBCR-UHFFFAOYSA-H

Inchi：

1S/Co.6HNO2.3Na/c;6*2-1-3;;;/h;6*(H,2,3);;;/q+3;;;;;;;3*+1/p-6

SMILES：

[Co+3].[Na+].[Na+].[Na+].[O-]N=O.[O-]N=O.[O-]N=O.[O-]N=O.[O-]N=O.[O-]N=O

六硝基钴(III)酸钠(14649-73-1)物化性质

实验特性

LogP : 1.50360
PSA : 314.94000
Merck : 14,8603
水溶性 : Very soluble in water
沸点 : °Cat760mmHg
熔点 : 220 °C (dec.)(lit.)
蒸气压 : No data available
闪点 : °C
颜色与性状 : 黄色结晶粉末
溶解性 : 未确定
密度 : g/cm3

计算特性

精确分子量 : 403.86000
氢键供体数量 : 0
氢键受体数量 : 18
可旋转化学键数量 : 0
同位素质量 : 403.86
重原子数量 : 22
复杂度 : 7.5
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 10
疏水参数计算参考值（XlogP） : 无
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 315

六硝基钴(III)酸钠(14649-73-1)安全信息

RTECS号： GF9480000
WGK Germany： 3
安全说明： S17; S26; S36/37
风险术语： R8; R36/37/38; R42/43
危险品标志： O Xn
危险品运输编号： UN 1479 5.1/PG 2
危害声明：H303吞入可能有害+H313皮肤接触可能有害+H333吸入可能对身体有害
警示性声明：P264处理后彻底清洗+P280戴防护手套/穿防护服/戴防护眼罩/戴防护面具+P305如果进入眼睛+P351用水小心冲洗几分钟+P338取出隐形眼镜（如果有）并且易于操作,继续冲洗+P337如果眼睛刺激持续+P313获得医疗建议/护理
储存条件： Ambient temperatures.
危险类别码： 8-36/37/38-42/43
信号词： warning
TSCA： Yes
HazardClass： 5.1

六硝基钴(III)酸钠(14649-73-1)推荐厂家更多厂家(7)

公司名称	手机号/电话	联系人	QQ	询单
上海吉至生化科技有限公司	18117592386 021-57481218	吉至试剂	3007522982	询单
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上海创赛科技有限公司	15021221957 021-59553580	凌度	2852351983	询单
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铼博（上海）生化科技有限公司	13311756052 021-60536361 13311756052 13311756131	张经理	2851717387	询单
上海阿拉丁生化科技股份有限公司	13167063860 13167063860	阿拉丁	3004013043	询单

六硝基钴(III)酸钠(14649-73-1)相关文献

1. Spectrophotometric determination of some oestrogens using sodium hexanitritocobaltate(III)
M. A. Korany,M. Abdel-Salam,A. M. Wahbi Analyst 1977 102 683
2. Colorimetric, spectrophotometric and fluorimetric determination of prenalterol hydrochloride
Abdel-Aziz M. Wahbi,Mohamed E. Mohamed,El Rasheed A. Gad Kariem,Hassan Y. Aboul-Enein Analyst 1983 108 886
3. Analytical chemistry
J. Chem. Soc. Abstr. 1904 86 B145
4. Nitro and related compounds
Joseph P. Adams,David S. Box J. Chem. Soc. Perkin Trans. 1 1999 749
5. CLXXVI.—Studies on the cobaltinitrites
Mary Cunningham,Frederick Mollwo Perkin J. Chem. Soc. Trans. 1909 95 1562
6. Analytical chemistry
J. Chem. Soc. Abstr. 1895 68 B84
7. Analytical chemistry
J. Chem. Soc. Abstr. 1882 42 94
8. Analytical chemistry
J. Chem. Soc. Abstr. 1900 78 B619
9. Analytical chemistry
J. Chem. Soc. Abstr. 1912 102 ii983
10. Spectrophotometric determination of isoprenaline sulphate and methyldopa using chloranil
Mohamed A. Korany,Abdel-Aziz M. Wahbi Analyst 1979 104 146

六硝基钴(III)酸钠(14649-73-1) MSDS

基础信息

Section 1: Product Identification
   Chemical Name:       Sodium hexanitritocobaltate (III), (ACS)
   CAS Registry Number:       14649-73-1
   Formula:       Na3Co(NO2)6
   EINECS Number:       none
   Chemical Family:       inorganic compound
   Synonym:       Sodium cobaltinitrate

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 14649-73-1 100% 0.02mg/m3 (as Co) no data

Section 3: Hazards Identification
   Harmful if swallowed. May cause cancer by inhalation. May cause slight to mild irritation of eyes, skin, and
   Emergency Overview:
   respiratory tract. May cause sensitization by inhalation and skin contact.
   Primary Routes of Exposure:       Inhalation, skin, eyes.
   Eye Contact:       May cause irritation, redness and pain.
   May cause irritation to the skin. Symptoms include redness, itching and pain. May cause sensitization through
   Skin Contact:
   skin contact.
   May cause irritation to the respiratory tract. Symptoms may include coughing, shortness of breath, respiratory
   Inhalation:
   hyper sensitivity and asthma.
   Causes abdominal pain, nausea, vomiting, flushing of the face and ears, mild hypotension, rash, and ringing in
   Ingestion:
   the ears.
   Harmful if swallowed. May cause cancer by inhalation. May cause irritation of the eyes, skin and respiratory
   Acute Health Affects:
   tract. May cause sensitization by inhalation and skin contact.
   Repeated oral administration of cobalt salts may reduce thyroid activity, cause blood disease, and damage
   Chronic Health Affects:       kidney, heart and lungs. Prolonged or repeated skin exposure may cause dermatitis. May cause cancer by
   inhalation.
   NTP:       No
   IARC:       Yes
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable
   Autoignition Temperature:       none
   Explosion Limits:       none
   Extinguishing Medium:       none required
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       None
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.

SECTION 7: Handling and Storage
Handling and Storage: Store material in a tightly sealed bottle away from moisture.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.
   Ventilation:       If possible, handle the material in an efficient fume hood.
   In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a
   Respirator:
   Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       orange pwdr.
   Molecular Weight:       403.98
   Melting Point:       no data
   Boiling Point:       no data
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       none
   Solubility in Water:       soluble

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable
   Hazardous Polymerization:       no hazardous polymerization
   Conditions to Avoid:       Contact with reducing agents
   Incompatibility:       Organic matter, reducing agents, active metals and halogens
   Decomposition Products:       oxides of nitrogen

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.
   Carcinogenic Effects:       Carcinogen
   Mutagenic Effects:       none
   Tetratogenic Effects:       none

SECTION 12: Ecological Information
   Avoid release to the environment. Very toxic to aquatic organisms. May cause long-term adverse effects in the
   Ecological Information:
   aquatic environment.

SECTION 13: Disposal Considerations
   This material and its container must be disposed of as hazardous waste according to local, state and federal
   Disposal:
   regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.
   SARA (Title 313):       Title compound: see category code N096 for reporting.
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A